Electric field-based frequency tuning of acoustic resonators at the material level may provide an enabling technology for building complex tunable filters. Tunable acoustic resonators were fabricated in thin plates (h/ λ ∼ 0.05 ) of X-cut lithium niobate (LiNbO) (90°, 90°, ψ = 170 ). LiNbO is known for its large electromechanical coupling ( K ) for the shear and symmetric Lamb modes (SH: K = 40 %, S: K = 30 %) in thin plates and, thus, applicability for low-insertion loss and wideband filter applications. We demonstrate the effect of a dc bias in X-cut LiNbO to shift the resonant frequency by ~0.4% through direct tuning of the resonator material. A nonlinear acoustic computation predicted 0.36% tuning, which was in excellent agreement with the tuning measurement. For X-cut, we predicted electrical tuning of the S mode up to 1.6% and for Y-cut the electrical tuning of the SH and S modes was up to 7.0% with K = 27.1 %. The mechanism is based on the nonlinearities that exist in the piezoelectric properties of LiNbO. The X-cut SH mode resonators were centered near 335 MHz and achieved a frequency tuning of 6 kHz/V through the application of a dc bias.
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http://dx.doi.org/10.1109/TUFFC.2019.2944174 | DOI Listing |
Chem Commun (Camb)
January 2025
Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany.
Calculated thermodynamic properties for the electrochemical glycerol oxidation at different temperatures and potentials indicate that external applied bias has a more significant influence on reaction selectivity than temperature.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Electrical Engineering and Electronics, The University of Liverpool, Brownlow Hill, L69 3GJ, UK.
This work quantifies, through use of molecular dynamics (MD) simulations, the kinetic rates of physical surface processes occurring at a plasma-water interface. The probabilities of adsorption, absorption, desorption and scattering were computed for O, NO, NO, NO, OH, HO, HNO, HNO, and NO as they interact with the interface at three water temperatures: 298 K, 323 K, and 348 K. Species are categorised into the short-residence group (O, NO, NO, and NO) and the long-residence group (OH, HO, HNO, HNO, and NO) based on their mean surface residence time.
View Article and Find Full Text PDFJ Org Chem
January 2025
Department of Chemistry, IIT Dharwad, Dharwad, Karnataka 580007, India.
The favorable redox properties of ferrocene have led to the extensive development of ferrocene-based systems for several electrochemical applications but have scarcely been explored for electrochromism. Here, we report the synthesis and electrochromic properties of novel π-conjugated ferrocene-dicyanovinylene systems (- and -). Monosubstituted (-) and disubstituted (-) compounds have been developed via Knoevenagel condensation of methyl-dicyanovinyl ferrocenes ( or ) with various aromatic aldehydes.
View Article and Find Full Text PDFMed Image Comput Comput Assist Interv
October 2024
Department of Biomedical Engineering, Yale University, New Haven, CT, USA.
Recent advancements in Contrastive Language-Image Pre-training (CLIP) [21] have demonstrated notable success in self-supervised representation learning across various tasks. However, the existing CLIP-like approaches often demand extensive GPU resources and prolonged training times due to the considerable size of the model and dataset, making them poor for medical applications, in which large datasets are not always common. Meanwhile, the language model prompts are mainly manually derived from labels tied to images, potentially overlooking the richness of information within training samples.
View Article and Find Full Text PDFChem Sci
January 2025
Hunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University Changsha 410083 P. R. China
The layer-stacking mode of a two-dimensional (2D) material plays a dominant role either in its topology or properties, but remains challenging to control. Herein, we developed alkali-metal ion-regulating synthetic control on the stacking structure of a vinylene-linked covalent triazine framework (termed spc-CTF) for improving hydrogen peroxide (HO) photoproduction. Upon the catalysis of EtONa in Knoevenagel polycondensation, a typical eclipsed stacking mode (spc-CTF-4@AA) was built, while a staggered one (spc-CTF-4@AB) was constructed using LiOH.
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