We show the spectra of advanced glycation products in response to recent comments made by Bratchenko . Our results suggest that information retrieved by Raman spectroscopy is relevant to screening diabetic patients, however, the comparison carried out in our paper, between ANN and SVM, was not fair, because of the erroneous PCA selection procedure and different sources of variation present in the analysis.
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http://dx.doi.org/10.1364/BOE.10.004492 | DOI Listing |
Dalton Trans
January 2025
Department of Chemistry, University of Alberta, 11227 Saskatchewan Dr, Edmonton, Alberta, T6G 2G2, Canada.
This article provides an alternative pathway towards cyclosilapentenes (, SiH2-iPr and SpiroSi) involving the use of Rieke magnesium to activate the requisite dienes for synthesis. Subsequent metal-mediated dehydrocoupling of cyclosilapentene and mixtures with another cyclogermapentene gives oligomers with backbone Si-Si (number average molecular weight, = 1.0 kDa) and Si-Ge ( = 1.
View Article and Find Full Text PDFSmall
January 2025
School of Materials and Chemical Engineering, Xuzhou University of Technology, Xuzhou, 221018, P. R. China.
Constructing a built-in electric field (BIEF) within heterostructures has emerged as a compelling strategy for advancing electrocatalytic oxygen evolution reaction (OER) performance. Herein, the p-n type nanosheet array heterojunction NiP-NCDs-Co(OH)-NF are successfully prepared. The variation in interaction affinity between nitrogen within N-doped carbon dots (NCDs) and Ni/Co induces charge redistribution between Co and Ni in the NiP-NCDs-Co(OH)-NF-3 heterostructure, thereby enhancing the intensity of the BIEF, facilitating electron transfer, and markedly improving OER activity.
View Article and Find Full Text PDFChemistry
January 2025
Brandeis University, Chemistry, 415 South Street,, Waltham, 02453, UNITED STATES OF AMERICA.
We designed and synthesized three diacetylene monomers M1-M3 having two NH2 groups. As anticipated, the NH2 groups aided the preorganization of these monomers by N-H…N hydrogen bonding. In the crystals of monomer M1 and M2, the intermolecular N-H…N hydrogen bonding preorganized the diyne units in an orientation suitable for their topochemical polymerization, but in the case of monomer M3, the distance was slightly larger than that recommended for the topochemical reaction.
View Article and Find Full Text PDFAnal Methods
January 2025
Jiangsu Beier Machinery Co. Ltd, Jiangsu, 215600, China.
Plastic waste management is one of the key issues in global environmental protection. Integrating spectroscopy acquisition devices with deep learning algorithms has emerged as an effective method for rapid plastic classification. However, the challenges in collecting plastic samples and spectroscopy data have resulted in a limited number of data samples and an incomplete comparison of relevant classification algorithms.
View Article and Find Full Text PDFLangmuir
January 2025
School of Physics, East China University of Science and Technology, Shanghai 200237, China.
Black phosphorus (BP), a promising two-dimensional material, faces significant challenges for its applications due to its instability in air and water. Herein, molecular dynamics simulations reveal that a self-assembled ferrocene (FeCp) molecular layer can form on BP surfaces and remain stable in aqueous environments, predicting its effectiveness for passivation. This theoretical finding is corroborated by X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, and optical microscopy observations.
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