The vanadium redox flow battery is considered one of the most promising candidates for use in large-scale energy storage systems. However, its commercialization has been hindered due to the high manufacturing cost of the vanadium electrolyte, which is currently prepared using a costly electrolysis method with limited productivity. In this work, we present a simpler method for chemical production of impurity-free V electrolyte by utilizing formic acid as a reducing agent and Pt/C as a catalyst. With the catalytic reduction of V electrolyte, a high quality V electrolyte was successfully produced and excellent cell performance was achieved. Based on the result, a prototype catalytic reactor employing Pt/C-decorated carbon felt was designed, and high-speed, continuous production of V electrolyte in this manner was demonstrated with the reactor. This invention offers a simple but practical strategy to reduce the production cost of V electrolyte while retaining quality that is adequate for high-performance operations.
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http://dx.doi.org/10.1038/s41467-019-12363-7 | DOI Listing |
Soft Matter
September 2024
Department of Intelligent Mechanical Engineering, Fukuoka Institute of Technology, Japan.
Electromechanical instability (EMI) restricts the performance of dielectric elastomer actuators (DEAs), leading to premature electrical breakdown at a certain voltage. However, macro-level observations using traditional carbon grease electrodes have failed to capture the detailed features of EMI. In this study, we investigated EMI at the microscopic scale by fabricating transparent and conductive single-walled carbon nanotube (SWCNT) electrodes.
View Article and Find Full Text PDFSmall
April 2023
Electronic Materials Research Center, Korea Institute of Science and Technology Seoul, Seoul, 02792, South Korea.
Thermoelectric technology, which has been receiving attention as a sustainable energy source, has limited applications because of its relatively low conversion efficiency. To broaden their application scope, thermoelectric materials require a high dimensionless figure of merit (ZT). Porous structuring of a thermoelectric material is a promising approach to enhance ZT by reducing its thermal conductivity.
View Article and Find Full Text PDFAppl Radiat Isot
June 2021
Department of Physics, Government College University Lahore, Lahore, 54000, Pakistan.
Diagnostics field is facilitated with advancements enacted in anatomic imaging (cross-sectional modalities). Radionuclide scans (imaging) escorted by Ga are extensively beneficial in bone scintigraphy and recognition of prosthetic joint failure. Present work comprises the data concerning Ga production via α-particle induced nuclear reactions, TTY (thick target yield) and impurity analysis.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2021
Chemistry of Interfaces, Luleå University of Technology, SE-97 187, Luleå, Sweden. and Department of Physics, Warwick University, CV4 7AL, Covertly, UK.
It was found that Li[BOB]·nH2O salts were not readily suitable for the synthesis of high-purity orthoborate-based tetraalkylphosphonium ionic liquids, as exemplified here for trihexyl(tetradecyl)phosphonium bis(oxalato)borate, [P6,6,6,14][BOB]; along with [BOB]-, a metastable transition anionic complex (TAC) of dihydroxy(oxalato)borate with oxalic acid, [B(C2O4)(OH)2·(HOOC-COOH)]-, was also formed and passed into the ionic liquid in the course of the metathesis reaction with trihexyl(tetradecyl)phosphonium chloride. On the contrary, Na[BOB] was found to be a more suitable reagent for the synthesis of this IL, because [BOB]- anions safely passed into the final IL without hydrolysis, when metathesis reactions were performed using aqueous-free media. Since ultra-pure Na[BOB] is not commercially available, in this work, a preparation protocol for ultra-pure (>99%) Na[BOB] was developed: (i) molar ratios of boric and oxalic acids were optimised to minimise boron-containing impurities, (ii) the Na[BOB] product was thoroughly purified by sequential washing of a fine powder product in hot acetonitrile and ethanol and (iii) characterised using powder X-ray diffraction and solid-state 11B MAS NMR spectroscopy.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
October 2020
Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, Yunnan, China.
Black phosphorus quantum dots (BPQDs), a type of nanoscale black phosphorus (BP), have fantastic application prospects in various fields. However, the premise of the application of BPQDs depends on its effective preparation. At present, most of preparation processes of BPQDs involve in organic solvents which may be harmful to humans and the environment.
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