Partially disordered TiO nanotube photonic crystal: randomness characterization and tuning of reflected scattering light.

Introducing disorder into a periodic nanostructure can lead to specific optical behaviors. We present a method of anodic oxidation by adjusting the applied voltage and process time to introduce disorder to TiO nanotubes. The surface morphology of TiO was numerically investigated according to the morphologies measured with a scanning electron microscope by imaging processing and a statistical method. TiO nanotubes obtained under different fabrication conditions have various tube radii ranging from 20-40 nm and wall thicknesses ranging from 20-70 nm. We also evaluated the degree of disorder of the tube radius of the TiO nanotubes. The reflected scattering light distributions of laser sources were optically measured at different observing distances, which indicate that the presence of nanotubes enhances the scattering effect, reducing the scattered light intensity by more than 75%, and provide the relationship between the scattering effect and surface morphology of nanotubes. This discovery offers TiO nanotubes important application prospects in optical limiting and light confinement, such as stealth coating.