Conversion of wastes to biofuels is a promising route to provide renewable low-carbon fuels, based on a low- or negative-cost feedstock, whose use can avoid negative environmental impacts of conventional waste treatment. However, current policies that employ LCA as a quantitative measure are not adequate for assessing this type of fuel, given their cross-sector interactions and multiple potential product/service streams (energy, fuels, materials, waste treatment service). We employ a case study of butanol and ethanol production from mixed municipal solid waste to demonstrate the challenges in using life cycle assessment to appropriately inform decision-makers. Greenhouse gas emissions results vary from -566 gCO eq/MJ (under US policies that employ system expansion approach) to +86 gCO eq/MJ and +23 gCO eq/MJ (under initial and current EU policies that employ energy-based allocation), relative to gasoline emissions of +94 gCO eq. LCA methods used in existing policies thus provide contradictory information to decision-makers regarding the potential for waste-based biofuels. A key factor differentiating life cycle assessment methodologies is the inclusion of avoided impacts of conventional waste treatment in US policies and their exclusion in EU policies. Present EU rules risk discouraging the valorisation of wastes to biofuels thus forcing waste toward lower-value treatment processes and products.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1021/acs.est.9b04286 | DOI Listing |
Int J Biol Macromol
January 2025
School of Environment and Resource, Key Laboratory of Solid Waste Treatment and Resource Recycle of Ministry of Education, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China.
Recently, multi-enzyme cascade catalysis has attracted increasing attention due to the advantages of integrating multiple enzymes, few side reactions and high catalytic efficiency. Herein, a novel dual-enzyme cascade system (GOx-FMt-HRP) was developed through cofactor-directed orientational co-immobilization of glucose oxidase (GOx) and horseradish peroxidase (HRP) onto functional montmorillonite (FMt). The presented method realizes the reconstitution of cofactors and apo-enzymes (enzymes without cofactors), which enables enzymes to be immobilized in specific orientations on the support, thereby effectively reducing changes in their conformation.
View Article and Find Full Text PDFEnviron Res
January 2025
The Key Laboratory of Environmental Pollution Health Risk Assessment, Research Center of Emerging Contaminants, South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, P.R. China.
Organic contaminants (OCs) are released into the environment through effluent discharges from wastewater treatment plants (WWTP), posing risks to environment health. However, emissions from various source, particularly large-scale investigations across different industries, remain poorly understood. Based on both sampling and statistical data, this study estimates the emissions of 10 OCs, including perfluorooctane acid (PFOA), perfluorooctane sulfonate (PFOS), 4-nonylphenol (4-NP), 4-tert-octylphenol (4-t-OP), dibutyl phthalate (DBP), di-iso-butyl phthalate (DIBP), dimethyl phthalate (DMP), butyl benzyl phthalate (BBP), di(2-ethylhexyl) phthalate (DEHP), and bisphenol A (BPA), from the effluents of 160 factories across 8 industries, 541 municipal wastewater treatment plants (MWWTPs), and 8 waste treatment plants (WTPs) in the upper Yangtze River Basin.
View Article and Find Full Text PDFSci Total Environ
January 2025
Material Flow Management and Resource Economy, Institute IWAR, Technical University of Darmstadt, Franziska-Braun-Straße 7, 64287 Darmstadt, Germany.
Nutrient circularity, an exemplification of circular economy (CE), is situated in the waste/wastewater-agriculture nexus. Recycling nutrient elements from waste streams to fertilizer products amplify the sustainable management of resources and intersect technical and biological loops, a concept developed for CE. Such a complex system needs to be directed by robust assessment methods such as life cycle assessment (LCA) to identify trade-offs and potentials.
View Article and Find Full Text PDFWaste Manag
January 2025
Earth Sciences Department, University of Turin 10125 Turin, Italy.
This study investigates steam washing (SW) as an innovative pretreatment for municipal solid waste incineration fly ash (MSWI-FA) dechlorination, useful for a more effective stabilization in cementitious matrix. By using a detailed analytical approach (XRPD, XRF, ICP-MS, IRMS, SEM) and geochemical modeling, great focus is dedicated on pollutant leaching reduction and changes in ash physicochemical characteristics as a function of exposure time. The research demonstrates that SW removes up to 70 % cadmium, 17 % zinc, and 10 % lead, primarily by dissolving the soluble and carbonate/hydroxide fractions and promoting the reprecipitation and adsorption of heavy metals into more stable compounds.
View Article and Find Full Text PDFWorld J Gastroenterol
January 2025
Department of Gastroenterology, The Seventh Affiliated Hospital of Sun Yat-sen University, Shenzhen 518000, Guangdong Province, China.
Background: (), is a prevalent parasitic worm that infects humans. It is found all over the world, particularly in tropical and subtropical areas. Strongyloidiasis is caused mostly by the parasitic nematode .
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!