We investigate the discrete diffraction phenomenon in a Polymer-Liquid Crystal-Polymer Slices (POLICRYPS) overlaying a random distribution of gold nanoparticles (AuNPs, plasmonic elements). We study the propagation of a CW green laser beam through the waveguide structure as a function of beam polarization, laser intensity and sample temperature. It turns out that the plasmonic field created at the interface between AuNPs and POLICRYPS waveguides enables and stabilizes the optical field propagation within the responsive nematic liquid crystal channels. The active role of the liquid crystal is pointed out by a polarization, temperature and beam divergence experimental analysis and evidenced by a peculiar trumpet-shaped discrete diffraction pattern. Theoretical simulations confirm that the observed optical behavior is governed by the interaction of the nematic liquid crystal with optical and plasmonic fields.
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http://dx.doi.org/10.1039/c9nr06917h | DOI Listing |
Angew Chem Int Ed Engl
January 2025
KU Leuven: Katholieke Universiteit Leuven, Chemistry, BELGIUM.
Understanding the impact of oxidative modification on protein structure and functions is essential for developing therapeutic strategies to combat macromolecular damage and cell death. However, selectively inducing oxidative modifications in proteins remains challenging. Herein we demonstrate that [V6O13{(OCH2)3CCH2OH}2]2- (V6-OH) hybrid metal-oxo cluster can be used for selective protein oxidative cleavage and modifications.
View Article and Find Full Text PDFInorg Chem
January 2025
Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India.
Metal complexes with tunable ligands play a crucial role in olefin polymerization and impart control over molecular weight, crystallinity, and stereoregularity. We report the single-step synthesis of imine-phenoxy ligands in excellent yields (81-93%). The identity of electronically tuned imine-phenoxy ligands was unambiguously ascertained by using a combination of spectroscopic and analytical methods.
View Article and Find Full Text PDFMolecules
November 2024
Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102A, HR-10000 Zagreb, Croatia.
In this study, we report the syntheses, crystal structures and magnetic properties of ternary copper(II) coordination compounds with l-homoserine (l-Hhser) and 1,10-phenanthroline (phen). Six new coordination compounds were obtained: [Cu(l-hser)(HO)(phen)]SO·5HO (), [Cu(μ-l-hser)(HO)(phen)][Cu(l-hser)(HO)(phen)](SO)∙12HO (), {[Cu(μ-l-hser)(HO)(phen)][Cu(μ-l-hser)(phen)]SO·6HO} (), {[Cu(μ-l-hser)(HO)(phen)]SO·3HO} (), [Cu(l-hser)(HO)(phen)][Cu(l-hser)(CHOH)(phen)]SO·4HO () and {[Cu(l-hser)(CHOH)(phen)][Cu(μ-l-hser)(phen)]SO·5CHOH} () It was shown that slight differences in water content in the synthetic mixtures highly influence the final product, so in some cases, two or three different products were obtained. The compounds were characterized by single-crystal X-ray diffraction and ESR spectroscopy.
View Article and Find Full Text PDFBiomed Opt Express
December 2024
Department of Ophthalmology, Stanford University, Palo Alto, CA 94303, USA.
We explore camera-based pupil tracking using high-level programming in computing platforms with end-user discrete and integrated central processing units (CPUs) and graphics processing units (GPUs), seeking low calculation latencies previously achieved with specialized hardware and programming (Kowalski et al., [Biomed. Opt.
View Article and Find Full Text PDFSmall
December 2024
Department of Food Science, College of Agriculture and Life Sciences, Cornell University, Ithaca, NY, 14853, USA.
Woven covalent organic frameworks (COFs) offer immense potential as photoactive materials because Cu(I) complexes are periodically integrated into the COF structure via a single synthetic step. A photoactive interlocking (woven) COF featuring Cu(I) photosensitizers that are spatially isolated and periodically arranged in three dimensions has been successfully synthesized and characterized. The optoelectronic properties of this COF, such as light absorption and photocatalytic performance toward the degradation of sulfamethoxazole (SMX) under visible light, are investigated.
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