Nanosilica particles were utilized as secondary reinforcement to enhance the strength of the epoxy resin matrix. Thin glass fibre reinforced polymer (GFRP) composite laminates of 3 ± 0.25 mm were developed with E-Glass mats of 610 GSM and LY556 epoxy resin. Nanosilica fillers were mixed with epoxy resin in the order of 0.25, 0.5, 0.75 and 1 wt% through mechanical stirring followed by an ultrasonication method. Thereafter, the damage was induced on toughened laminates through low-velocity drop weight impact tests and the induced damage was assessed through an image analysis tool. The residual compression strength of the impacted laminates was assessed through compression after impact (CAI) experiments. Laminates with nanosilica as secondary reinforcement exhibited enhanced compression strength, stiffness, and damage suppression. Results of Fourier-transform infrared spectroscopy revealed that physical toughening mechanisms enhanced the strength of the nanoparticle-reinforced composite. Failure analysis of the damaged area through scanning electron microscopy (SEM) evidenced the presence of key toughening mechanisms like damage containment through micro-cracks, enhanced fiber-matrix bonding, and load transfer.
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http://dx.doi.org/10.3390/ma12193057 | DOI Listing |
Nanomaterials (Basel)
March 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
To significantly improve the tribological performance of epoxy resin (EP), a novel h-BN/MoS composite was successfully synthesized using spherical MoS particles with lamellar self-assembly generated through the calcination method, followed by utilizing the "bridging effect" of a silane coupling agent to achieve a uniform and vertically oriented decoration of hexagonal boron nitride (h-BN) nanosheets on the MoS surface. The chemical composition and microstructure of the h-BN/MoS composite were systematically investigated. Furthermore, the enhancement effect of composites with various contents on the frictional properties of epoxy coatings was studied, and the mechanism was elucidated.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2025
Northwestern Polytechnical University, School of Chemistry and Chemical Engineering, CHINA.
Epoxy resin with high thermal conductivity (λ) are widely used in electronic packaging, bonding, and coating. However, those with high intrinsic λ, typically synthesized using biphenyl or aromatic rings extended by ester linkages as the mesogenic unit, often exhibit high liquid crystal transition temperatures and poor processability. In this study, a series of naphthalene-based liquid crystal epoxy monomers (LCE) were synthesized, using naphthalene as the mesogenic unit and modifying the flexible chain length on both sides.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
College of Materials, Fujian Provincial Key Laboratory of Fire Retardant Materials, Xiamen Key Laboratory of Fire Retardant Materials, Xiamen University, Xiamen, Fujian 361005, China.
In recent years, waterborne epoxy resin (WE) has garnered attention due to its lower environmental pollution compared to solvent-based coatings. However, their poor barrier properties severely limit their practical applications. In order to enhance the corrosion resistance of water-based epoxy resin coating, a highly efficient strategy of combining the barrier effect of lamellar structured zirconium phosphate (α-ZrP) and the inhibitor effect of special carbon dots by the intercalation method was proposed in this work.
View Article and Find Full Text PDFSmall
March 2025
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China.
Compared to the traditional slurry-coating process, the solvent-free manufacturing process holds significant potential due to its advantages, including economic viability, thick electrodes, and avoidance of organic solvents. However, the currently dominant solvent-free process suffers from poor mechanical properties and electrochemical instability. Herein, a conductive binder (M@EP), composed of multi-walled carbon nanotubes (MWNT) and epoxy resin-based binders (EP), is designed and synthesized.
View Article and Find Full Text PDFBMC Oral Health
March 2025
Faculty of Dentistry Department of Endodontics, Yeditepe University, İstanbul, Türkiye.
Background: Endodontic sealers are expected to provide a favorable adhesion for a successful seal. This study aimed to evaluate the effect of ethylenediaminetetraacetic acid (EDTA) and Hydroxyethylidene Diphosphonic acid (HEDP) on bond strength of AH Plus and EndoSequence BC HiFlow sealers to root canal walls.
Methods: This study utilized 144 mandibular human premolars.
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