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Fabrication of Durable Ordered TaO Nanotube Arrays Decorated with BiS Quantum Dots. | LitMetric

AI Article Synopsis

Article Abstract

One of the most important challenges in the fabrication of ordered tantalum pentaoxide (TaO) nanotube arrays (NTs) via the electrochemical method is the formation of nanotubes that adhere well to the Ta substrate. In this paper, we propose a new protocol that allows tight-fitting TaO nanotubes to be obtained through the anodic oxidation of tantalum foil. Moreover, to enhance their activity in the photocatalytic reaction, in this study, they have been decorated by nontoxic bismuth sulfide (BiS) quantum dots (QDs) via a simple successive ionic layer adsorption and reaction (SILAR) method. Transmission electron microscopy (TEM) analysis revealed that quantum dots with a size in the range of 6-11 nm were located both inside and on the external surfaces of the TaO NTs. The effect of the anodization time and annealing conditions, as well as the effect of cycle numbers in the SILAR method, on the surface properties and photoactivity of TaO nanotubes and BiS/TaO composites have been investigated. The TaO nanotubes decorated with BiS QDs exhibit high photocatalytic activity in the toluene degradation reaction, i.e., 99% of toluene (C = 200 ppm) was degraded after 5 min of UV-Vis irradiation. Therefore, the proposed anodic oxidation of tantalum (Ta) foil followed by SILAR decorating allows a photocatalytic surface, ready to use for pollutant degradation in the gas phase, to be obtained.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6835939PMC
http://dx.doi.org/10.3390/nano9101347DOI Listing

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