A versatile strategy for a facile approach to chemical graft MOFs onto polypyrrole nanotubes (PPyNTs@MOFs) is designed and fabricated rationally by means of 1,4-dibromobutane linkage. Various MOFs arranged randomly close-packed on PPyNTs, including Co, Cu, Zn, Mn, Fe, Al, Ti, Cr, Zr and V, have been synthesized successfully. The as-prepared PPyNT@UIO-66 hybrids, used as a cathode carrier, exhibit excellent cyclic stability in Li-S batteries via strong physical and chemical adsorption/affinity with polysulfides.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c9cc06362e | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
High-performance supercapacitors based on coarse nanofiber bundle and ordered network hydrogels.
Int J Biol Macromol
December 2024
Jiangsu Key Laboratory of Sericultural and Animal Biotechnology, School of Biotechnology, Jiangsu University of Science and Technology, Zhenjiang 212100, China; Key Laboratory of Silkworm and Mulberry Genetic Improvement, Ministry of Agriculture and Rural Affairs, Sericultural Scientific Research Center, Chinese Academy of Agricultural Sciences, Zhenjiang 212100, China.
Most of the developed flexible hydrogel supercapacitors struggle to maintain their electrochemical stability and structural integrity under tensile strain. Therefore, developing a flexible supercapacitor with excellent mechanical properties and stable electrochemical performance under different strains remains a challenge. Based on the previous cartilage-like structure, we designed a new coarse nanofiber bundle and ordered network.
View Article and Find Full Text PDFUltrafine metal-organic framework @ graphitic carbon with MoS-CNTs nanocomposites as carbon-based electrochemical sensor for ultrasensitive detection of catechin in beverages.
Mikrochim Acta
December 2024
Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, People's Republic of China.
GO/Co-MOF/PPy-350 (GPC-350) was synthesized by in situ growth of ultrafine Co-MOF on graphene oxide (GO), followed by encapsulation with polypyrrole (PPy) and calcination at 350.0℃. Meanwhile, MoS-MWCNTs (MoS-CNTs) were produced via the in situ synthesis of MoS within multi-walled carbon nanotubes (MWCNTs).
View Article and Find Full Text PDFSystematic design of MXene/thermoplastic polyurethane/carbon nanotube@polypyrrole fiber electrodes for efficient flexible fiber supercapacitors.
J Colloid Interface Sci
December 2024
School of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China.
MXene exhibits exceptional electrical and electrochemical properties, and is regarded as a promising candidate for future wearable electronic products. However, achieving a balance between flexibility and capacitance performance in MXene-based fiber supercapacitors remains a challenge. Here, MXene/Thermoplastic polyurethane (TPU) composite fibers with good conductivity and tensile properties, were prepared by wet spinning method.
View Article and Find Full Text PDFEncapsulating phase change materials into melamine formaldehyde sponge assembled with polypyrrole modified halloysite nanotube for effective solar-thermal energy storage and solar-thermal-electric conversion.
J Colloid Interface Sci
November 2024
School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, PR China.
Exploiting inexpensive composite phase change materials (PCMs) with comprehensive characteristics of high encapsulation efficiency, good leakage resistance, strong flexibility, high heat conductivity, and powerful light absorption is considerably imperative for their solar-thermal and solar-thermal-electric conversion. Herein, polypyrrole (PPy) modified halloysite (HNT/PPy) was assembled into the pores of melamine formaldehyde (MF) sponge to construct hierarchical porous structure (MHP), in which PPy serves as light absorber and heat conducting agent to consolidate the light absorption and thermal conductivity, while the interwoven HNT in MF not only acts as carrier to provide sufficient space for guaranteeing more PCMs' encapsulation, but also dramatically narrows MF's pore size and prevents PCMs' leakage. As expected, the MHP can encapsulate as high as 95 wt% of polyethylene glycol (PEG) with extremely high latent heat of 177.
View Article and Find Full Text PDFElectrochemical sensor based on molecularly imprinted polypyrrole-MWCNTs-OH/covalent organic framework for the detection of ofloxacin in water.
Mikrochim Acta
December 2024
Antibiotics Research and Re-Evaluation Key Laboratory of Sichuan Province, Sichuan Industrial Institute of Antibiotics, School of Pharmacy, Chengdu University, Chengdu, 610106, China.
A platform was developed to accurately detect the content of ofloxacin (OFX) based on molecularly imprinted polypyrrole-MWCNTs-OH/1,3,5-Tris(4-aminophenyl) benzene (TAPB)-2,5-dimethoxybenzene-1,4-dicarboxaldehyde (DMTP)-covalent organic framework (MIP-MWCNTs-OH/COF)-modified glassy carbon electrode (GCE) sensor (MIP-MWCNTs-OH/COF/GCE). The complex of MWCNTs-OH and COF synergistically enhanced the active area and electrochemical signal, based on which a molecularly imprinted membrane was polymerized on its surface to further improve the selectivity. Under optimized conditions, the prepared MIP-MWCNTs-OH/COF/GCE sensor exhibited strong detection performance to OFX in a linear range 1.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!