In the present work, carbonate samples covering wall painting of four points in the same site found at Peruaçu National Park in the extreme northwest of the state of Minas Gerais, Brazil, has been investigated and dated by thermoluminescence (TL) and electron paramagnetic resonance (EPR) techniques. The EPR spectrum of the carbonate samples presented the typical six signals due to Mn ion and signals around g~2.0 due to SO and CO. The thermal stability and dose response of the EPR signals were found to be suitable for an age determination using the center due to CO. The carbonate sample exhibits TL peaks at approximately 350 °C. TL and EPR dating of the carbonate samples that covered the cave paintings gave an age of 33.13 to 48.40 ka. This series of dating data indicate that in the region about 220-250 km from the coast and extending from the State of Piaui, Bahia to Minas Gerais people lived around 50000 years ago.
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http://dx.doi.org/10.1016/j.apradiso.2019.108847 | DOI Listing |
Int J Biol Macromol
January 2025
Department of Chemistry, Rutgers University, Camden, NJ, United States of America; Center for Computational and Integrative Biology, Rutgers University, Camden, NJ, United States of America. Electronic address:
Ion transport in solid polymer electrolytes is crucial for applications like energy conversion and storage, as well as carbon dioxide capture. However, most of the materials studied in this area are petroleum-based. Natural materials (biopolymers) have the potential to act as alternatives to petroleum-based products and, when derived with ionic liquid (IL) functionalities, present a sustainable alternative for conductive materials by offering tunable morphological, thermal, and mechanical properties.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Geotechnologies in Soil Sciences Research Group - GeoCiS, Department of Soil Science, Luiz de Queiroz College of Agriculture - Esalq, University of São Paulo - USP, Piracicaba, São Paulo, Brazil. Electronic address:
Analyzing soil in large and remote areas such as the Amazon River Basin (ARB) is unviable when it is entirely performed by wet labs using traditional methods due to the scarcity of labs and the significant workforce requirements, increasing costs, time, and waste. Remote sensing, combined with cloud computing, enhances soil analysis by modeling soil from spectral data and overcoming the limitations of traditional methods. We verified the potential of soil spectroscopy in conjunction with cloud-based computing to predict soil organic carbon (SOC) and particle size (sand, silt, and clay) content from the Amazon region.
View Article and Find Full Text PDFFood Chem
January 2025
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China. Electronic address:
Carbon dots (CDs), one type of zero-dimensional carbon nanomaterial, showed extensive application in food analysis. Herein, CDs as fluorometry and colorimetry probes were developed to determine peroxydisulfate (PDS) and phosphate ion (Pi) in food samples. CDs were developed with one-pot hydrothermal process from 5-amino salicylic acid and o/m-phenylenediamine named o/m-CDs.
View Article and Find Full Text PDFFood Chem
January 2025
Materials Research Institute and Department of Ecosystem Science and Management, 204 Energy and the Environment Laboratory, The Pennsylvania State University, University Park, PA 16802, USA. Electronic address:
This work presents a convenient and easy-to-operate method for synthesizing the functionally integrated nanocomposite of nitrogen-doped multi walled carbon nanotube networks (N-CNTs) and cobalt 2-methylimidazole (ZIF-67) nanoparticles. The N-CNTs@ZIF-67 nanocomposite was utilized to design a novel electrochemical sensing platform for detecting gallic acid (GA). The N-CNTs@ZIF-67 modified glass carbon electrode (GCE) demonstrated high sensitivity for GA electrochemical detection (LOD: 10.
View Article and Find Full Text PDFFood Chem
January 2025
School of Public Health, Hebei Key Laboratory of Occupational Health and Safety for Coal Industry, North China University of Science and Technology, Tangshan 063210, Hebei, China. Electronic address:
Effective and convenient QuEChERS of lipophilic pesticides with wide pK range from strongly pigment-rich food samples remains a great challenge. Here, a ZIF-67 derived magnetic nanoporous carbon (Co@MPC) was firstly proposed for modified QuEChERS of carbamate pesticides (pK 4.3-12.
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