A copper-catalyzed silylation of propargyl dichlorides was developed to access chloro-substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro-substituted allenylsilanes can be synthesized in moderate to high yields and good enantioselectivities with this protocol.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899605 | PMC |
| http://dx.doi.org/10.1002/anie.201908343 | DOI Listing |
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