While commercially available suncare products are effective at absorbing ultraviolet (UV)-light, recent studies indicate systemic toxicities associated with many traditional chemical and physical UV-filters. We demonstrate the application of xanthommatin, a biochrome present in arthropods and cephalopods, as an alternative chemical UV-filter that is cytocompatible while maintaining its photostability and photoprotective properties.
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http://dx.doi.org/10.1039/c9cc06323d | DOI Listing |
Dalton Trans
April 2024
University of Monastir, Laboratory of Physical Chemistry of Materials (LR01ES19), Faculty of Sciences of Monastir, Avenue of the Environment, 5019 Monastir, Tunisia.
Recent advances in visible light photocatalysis represent a significant stride towards sustainable catalytic chemistry. However, its successful implementation in fine chemical production remains challenging and requires careful optimization of available photocatalysts. Our work aims to structurally modify bioinspired porphyrin catalysts, addressing issues related to their laborious synthesis and low solubility, with the goal of increasing their efficiency and developing reusable catalytic systems.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
February 2024
State Key Laboratory of Organometallic Chemistry, Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai, 200032, P. R. China.
Polypeptides, as natural polyelectrolytes, are assembled into tailored proteins to integrate chromophores and catalytic sites for photosynthesis. Mimicking nature to create the water-soluble nanoassemblies from synthetic polyelectrolytes and photocatalytic molecular species for artificial photosynthesis is still rare. Here, we report the enhancement of the full-spectrum solar-light-driven H production within a supramolecular system built by the co-assembly of anionic metalloporphyrins with cationic polyelectrolytes in water.
View Article and Find Full Text PDFACS Nano
January 2024
CNR NANOTEC-Istituto di Nanotecnologia, c/o Campus Ecotekne, Via Monteroni, 73100 Lecce, Italy.
Fostered by the top power conversion efficiencies (PCEs) of lab-scale devices, industrialization of perovskite solar cells is underway. Nevertheless, the intrinsically poor stability of these materials still represents a major concern. Herein, inspired by Nature, the use of β-carotene in perovskite solar cells is proposed to mimic its role as a protective pigment, as occurs in natural photosynthesis.
View Article and Find Full Text PDFChem Sci
December 2023
URD Agro-Biotechnologies Industrielles (ABI), CEBB, AgroParisTech 51110 Pomacle France
Sinapoyl malate, naturally present in plants, has proved to be an exceptional UV filter and molecular heater for plants. Although there are nowadays industrially relevant sustainable synthetic routes to sinapoyl malate, its incorporation into certain cosmetic formulations, as well as its adsorption on plant leaves, is limited by its hydrophilicity. To overcome these obstacles, it is important to find a way to effectively control the hydrophilic-lipophilic balance of sinapoyl malate to make it readily compatible with the cosmetic formulations and stick on the waxy cuticle of leaves.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2023
Department of Chemistry, Pohang University of Science and Technology (POSTECH), Gyeongbuk, 37673, Republic of Korea.
Aryl alcohol-type or phenolic fluorophores offer diverse opportunities for developing bioimaging agents and fluorescence probes. Due to the inherently acidic hydroxyl functionality, phenolic fluorophores provide pH-dependent emission signals. Therefore, except for developing pH probes, the pH-dependent nature of phenolic fluorophores should be considered in bioimaging applications but has been neglected.
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