A multitude of applications is related to the unique properties of absorption, scattering, and plasmon-enhanced phenomena of metal nanoparticles (MNPs). The aqueous colloidal-based synthesis of MNPs is used more widely as it allows precise shape and size control. However, for various applications, it is required to have the MNPs in an organic solvent or polymer that is compatible with the MNPs. This work establishes a protocol from the synthesis to the phase transfer process of gold nanorods and gold core silver shell nanocuboids (Au@Ag NCs) in dichloromethane. Subsequent dispersion in a polymer (silicone encapsulant polymer) is achieved while retaining the MNPs' plasmonic properties. Au@Ag NCs have not been transferred to an organic solvent to date due to their unique shape and instability in the organic phase. The established protocol is reproducible, and MNPs were found to be stable for up to a year in the polymer. Qualitative and quantitative validation of the experimental results is achieved on MNP concentration by a model based on the finite difference time domain method. Using the model, the concentration of MNPs in nanocomposite can be determined.
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