Model-Free Measurement of the Pair Potential in Colloidal Fluids Using Optical Microscopy.

Phys Rev Lett

Department of Chemistry, Physical & Theoretical Chemistry Laboratory, University of Oxford, Oxford OX1 3QZ, United Kingdom.

Published: August 2019

We report a straightforward, model-free approach for measuring pair potentials from particle-coordinate data, based on enforcing consistency between the pair distribution function measured separately by the distance-histogram and test-particle insertion routes. We demonstrate the method's accuracy and versatility in simulations of simple fluids, before applying it to an experimental system composed of superparamagnetic colloidal particles. The method will enable experimental investigations into many-body interactions and allow for effective coarse graining of interactions from simulations.

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http://dx.doi.org/10.1103/PhysRevLett.123.098002DOI Listing

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