Fabrication of P(AN-MA)/rGO-g-PAO Superhydrophilic Nanofiber Membrane for Removal of Heavy Metal Ions.

J Nanosci Nanotechnol

State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Municipal Key Laboratory of Advanced Fiber and Energy Storage, School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China.

Published: March 2020

The process in which the nanofiber membrane is used to remove heavy metal ions and separation of oil-water solution is analyzed. Herein, smooth structures are induced by rGO-g-PAO sheets, which could be attributed to the strong interaction between P(AN-MA) and rGO-g-PAO. It is rewarding to note that the P(AN-MA)/rGO-g-PAO nanofiber membrane would exhibit superhydrophilic traits in the air and ultra-low oil-adhesive traits underwater when the concentration of P(AN-MA) and PAO is 13 wt.% and 0.3 wt.%, respectively. The amidoxime (-C(NH₂) NOH) groups on the membrane surface can efficiently adsorb copper (Cu(II)) (1.65 mmol/g) and chromium (Cr(VI)) (4.70 mmol/g) ions in the waste water. Meanwhile, the P(AN-MA)/rGO-g-PAO nanofiber membrane exhibits ultrahigh flux (~6150 LMH), satisfying rejection rate (~97%) and outstanding flux recovery ratio (~99%) in separating oil water emulsion.

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http://dx.doi.org/10.1166/jnn.2020.17147DOI Listing

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