Because of extreme three-dimensional field confinement and easy electrically tunability, plasmons in graphene nanostructures are promising candidates for many applications, such as biosensing, photodetectors and modulators. However, up to now, graphene plasmons have been explored mostly on substrates. Scatterers, corrugations and dopants induced by substrates not only add damping to plasmons but also obscure the intrinsic electronic properties of graphene. In this work, the near-field response of surface plasmons of suspended graphene circular resonators is studied with the scattering-type scanning near-field optical microscopy under different excitation wavelengths, λ = 10.653 and 10.22 μm, respectively. Fundamental and higher order breathing plasmon modes are revealed in real-space with the Fermi energy of graphene of only 0.132 eV. Moreover, the direct experimental evidence on near-field electric tuning in suspended graphene resonators is demonstrated by using back-gate tuning. Our work not only provides a foundation to truly understand the properties of electrons inside pure graphene, but shines light on the applications in optoelectronic devices with suspended two-dimensional materials.
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http://dx.doi.org/10.1088/1361-6528/ab4249 | DOI Listing |
Microsc Res Tech
December 2024
University of Science and Technology of China, Hefei, People's Republic of China.
Atomically resolved scanning tunneling microscope (STM) capable of in situ rotation in a narrow magnet bore has become a long-awaited but challenging technique in the field of strong correlation studies since it can introduce the orientation of the strong magnetic field as a control parameter. This article presents the design and functionality of a piezoelectrically driven rotatable STM (RSTM), operating within a 12 T cryogen-free magnet and achieving a base temperature below 1.8 K, along with spectroscopic capabilities.
View Article and Find Full Text PDFJ Chromatogr A
December 2024
Hebei Key Laboratory of Public Health Safety, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of Ministry of Education, College of Pharmaceutical Science, Hebei University, Baoding 071002, China; Hebei Key Laboratory of Analytical Science and Technology, State Key Laboratory of New Pharmaceutical Preparations and Excipients, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, China. Electronic address:
A novel adsorbent, second-generation polyester dendritic functionalized graphene oxide (PDG-2), was developed for pipette tip micro solid-phase extraction of venlafaxine and desvenlafaxine from urine. Leveraging the facile modification properties of graphene oxide and the controlled synthesis capabilities of dendritic materials, PDG-2 exhibited a rough surface and numerous active groups with adsorption capacities of desvenlafaxine and venlafaxine up to 187 mg g and 230 mg g. Method validation confirmed excellent linearity, low detection limits, high precision, and accurate recovery.
View Article and Find Full Text PDFMater Horiz
November 2024
Department of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Using mechanical force to induce chemical reactions with two-dimensional (2D) materials provides an approach for both understanding mechanochemical processes on the molecular level, and a potential method for using mechanical strain as a means of directing the functionalization of 2D materials. To investigate this, we have designed a modular experimental platform which allows for monitoring of reactions on strained graphene Raman spectroscopy as a function of time. Both the strain present in graphene and the corresponding chemical changes it undergoes in the presence of a reagent can be followed concomitantly.
View Article and Find Full Text PDFNanoscale
November 2024
Department of Mechanical Engineering, The Pennsylvania State University, University Park, Pennsylvania, 16802, USA.
Nanofluidics has made significant impacts and advancements in various fields, including ultrafiltration, water desalination, biomedical applications, and energy conversion. These advancements are driven by the distinct behavior of fluids at the nanoscale, where the solid-fluid interaction characteristic lengthscale is in the same order of magnitude as the flow conduits. A key challenge in nanofluidics is understanding hydrodynamic slip, a phenomenon in which fluids flow past solid boundaries with a non-zero surface velocity, deviating from the classical no-slip boundary condition.
View Article and Find Full Text PDFAdv Sci (Weinh)
November 2024
State Key Laboratory of Natural Medicines, China Pharmaceutical University, 639 Longmian Avenue, Nanjing, 211198, China.
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