We demonstrate a novel attoclock, in which we add a perturbative linearly polarized light field at 400 nm to calibrate the attoclock constructed by an intense circularly polarized field at 800 nm. This approach can be directly implemented to analyze the recent hot and controversial topics involving strong-field tunneling ionization. The generally accepted picture is that tunneling ionization is instantaneous and that the tunneling probability synchronizes with the laser electric field. Alternatively, recently it was described in the Wigner picture that tunneling ionization would occur with a certain of time delay. We unify the two seemingly opposite viewpoints within one theoretical framework, i.e., the strong-field approximation (SFA). We illustrate that both the instantaneous tunneling picture and the Wigner time delay picture that are derived from the SFA can interpret the measurement well. Our results show that the finite tunneling delay will accompany nonzero exit longitudinal momenta. This is not the case for the instantaneous tunneling picture, where the most probable exit longitudinal momentum would be zero.
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http://dx.doi.org/10.1103/PhysRevLett.123.073201 | DOI Listing |
This Letter describes the first, to the best of our knowledge, demonstration of a velocity measurement by nitric oxide ionization induced flow tagging and imaging (NiiFTI) of a high-enthalpy hypersonic flow utilizing naturally formed nitric oxide. The measurements were conducted in the hypervelocity expansion tunnel (HXT) at Texas A&M University in Mach 8.5 and Mach 10 flows near an ogive test article.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, P. R. China.
Alkali element doping has significant physical implications for two-dimensional materials, primarily by tuning the electronic structure and carrier concentration. It can enhance interface electronic interactions, providing opportunities for effective charge transfer at metal-organic interfaces. In this work, we investigated the effects of gradually increasing the level of K doping on the lattice structure and electronic properties of an organometallic coordinated Kagome lattice on a Ag(111) surface.
View Article and Find Full Text PDFPhys Chem Chem Phys
December 2024
JEOL Ltd, Akishima, Tokyo, 196-8558, Japan.
The McLafferty rearrangement (McLR) of the methyl valerate molecular ion has been comprehensively studied from the standpoints of the timescale for the keto-enol transformation and the change of the configuration of intermediates and transition state (TS), using mass spectrometry with electron ionization, strong-field tunnel ionization and collision-induced dissociation methods, and the global reaction route mapping (GRRM) program with quantum chemical calculations (QCCs). The timescales estimated from mass spectrometric results suggested that the McLR starts at 100 fs after ionization and is completed at least within 100 ns in the ion source. Whereas the timescales are consistent with a stepwise mechanism of fast (100 fs) and slow (10 ps) steps presented by Stamm , the QCCs put forth the possibility that an unanticipated, rapid, concerted process may be involved in completing the McLR reaction.
View Article and Find Full Text PDFJ Phys Chem A
November 2024
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0309, United States.
Characterization of the structural and electron transport properties of single chiral molecules provides critical insights into the interplay between their electronic structure and electrochemical environments, providing broader implications given the significance of molecular chirality in chiroptical applications and pharmaceutical sciences. Here, we examined the topographic and electronic features of a recently developed chiral molecule, B,N-embedded double hetero[7]helicene, at the edge of Cu(100)-supported NaCl thin film with scanning tunneling microscopy and spectroscopy. An electron transport energy gap of 3.
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