This article describes the modeling of the compaction/consolidation behavior of thermoplastic composite prepregs during the thermoforming process. The proposed model is principally based on a generalized Maxwell approach. Within a hyperelastic framework, viscoelasticity is introduced for the compaction mode in addition to the in-plane shearing mode by taking into account the influence of the resin and its flow during consolidation. To reveal the evolution of the consolidation level, which reflects the number of voids in the composite, an intimate contact model was used during the process. The model was characterized by a compaction test at a high temperature. It was implemented into a recently developed prismatic solid-shell finite element. The analysis of the thermoforming of a double dome demonstrated the relevance of the consolidation computation in determining the process parameters leading to a composite part free of voids.
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http://dx.doi.org/10.3390/ma12182853 | DOI Listing |
J Biomed Mater Res B Appl Biomater
February 2025
Department of Prosthodontics, College of Dentistry, University of Baghdad, Baghdad, Iraq.
While polyetherketoneketone is a high-performance thermoplastic polymer, its hydrophobicity and inertness limit bone adhesion. This study aimed to evaluate a novel PEKK/CaSiO/TeO nanocomposite, comparing it to PEKK/15 wt.% CaSiO and PEKK groups.
View Article and Find Full Text PDFBiomimetics (Basel)
January 2025
Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 3, 9747 AG Groningen, The Netherlands.
Wood plastic composites (WPCs) offer a means to reduce the carbon footprint by incorporating natural fibers to enhance the mechanical properties. However, there is limited information on the mechanical properties of these materials under hostile conditions. This study evaluated composites of polypropylene (PP), polystyrene (PS), and polylactic acid (PLA) processed via extrusion and injection molding.
View Article and Find Full Text PDFNanoscale
January 2025
School of Materials and Chemistry, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai 200093, China.
Thermoplastic polyurethane (TPU) fabrics often possess good mechanical, waterproofing, and breathability properties. However, the resistance of TPU to excessive ultraviolet (UV) irradiation is poor and often does not meet the UV resistance requirements of fabrics. Electrospun nanofibers with a side-by-side structure can combine the advantages of different materials.
View Article and Find Full Text PDFSci Bull (Beijing)
December 2024
State Key Laboratory of Advanced Fiber Materials, Institute of Functional Materials, College of Materials Science and Engineering, Research Base of Textile Materials for Flexible Electronics and Biomedical Applications (China Textile Engineering Society), Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative Medicine, Shanghai Key Laboratory of Lightweight Composite, Donghua University, Shanghai 201620, China. Electronic address:
It remains a challenge for a simple and scalable method to fabricate ultrathin porous Janus membranes for stretchable on-skin electronics. Here, we propose a one-step droplet spreading phase separation strategy to prepare an ultrathin and easily collected Janus thermoplastic polyurethane (TPU) membrane within seconds. The metal-ion solvation structure mitigated migration kinetics to delay TPU solution demixing, promoting the further penetration of the coagulating solvent.
View Article and Find Full Text PDFAdv Mater
January 2025
National Engineering Research Center for Colloidal Materials, School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, 250100, P. R. China.
The hardness of thermoplastic elastomers (TPEs) significantly influences their suitability for various applications, but traditionally, enhancing hardness reduces toughness. Herein a method is introduced that leverages hybrid soft segments to fine-tune the hardness of TPEs without compromising their exceptional toughness. Through the selective copolymerization of polytetramethylene ether glycols (PTMEGs) at various molecular weights, supramolecular poly(urethane-urea) TPEs are molecularly engineered to cover a wide spectrum of hardness while retaining good toughness.
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