Compound [Ag S (StBu) (CF COO) (CO )](CO ) ⋅CH Cl ⋅4CH OH⋅9DMF (1) has been obtained and well defined. It consists of a multi-shell structure involving two Ag centres, one Ag S pentagram, two Ag S pentagons and one Ag S shell. Compound 1 has been characterized by XPS, FT-IR, PXRD, TGA, NMR, MS, UV/Vis spectrum, TEM and cyclic voltammetry. Temperature-sensitive luminescent property of 1 has also been investigated.
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