Surface recombination at the photoanode/electrolyte junction seriously impedes photoelectrochemical (PEC) performance. Through coating of photoanodes with oxygen evolution catalysts, the photocurrent can be enhanced; however, current systems for water splitting still suffer from high recombination. We describe herein a novel charge transfer system designed with BiVO as a prototype. In this system, porphyrins act as an interfacial-charge-transfer mediator, like a volleyball setter, to efficiently suppress surface recombination through higher hole-transfer kinetics rather than as a traditional photosensitizer. Furthermore, we found that the introduction of a "setter" can ensure a long lifetime of charge carriers at the photoanode/electrolyte interface. This simple interface charge-modulation system exhibits increased photocurrent density from 0.68 to 4.75 mA cm and provides a promising design strategy for efficient photogenerated charge separation to improve PEC performance.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201908833 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Solvent Selection as a Key Factor in the Performance of Semitransparent Heterojunctions Composed of Hydrogenated Nanotubes and Bismuth Sulfides.
ACS Appl Mater Interfaces
January 2025
Centre for Plasma and Laser Engineering, Institute of Fluid-Flow Machinery, Polish Academy of Sciences, 14 Fiszera Street, 80-231 Gdańsk, Poland.
Research on titanium nanotubes modified with metal sulfides, particularly bismuth sulfide (BiS), aims to create heterostructures that efficiently absorb sunlight and then separate photogenerated charge carriers, thereby enhancing the energy conversion efficiency. This study shows a key role of solvent used for sulfide and bismuth salt solutions used during successive ionic layer adsorption and reaction (SILAR) onto the morphology, structure, and photoresponse of the heterojunction where one element is represented by semitransparent titania nanotubes (gTiNT) and the second is BiS. Using 2-methoxyethanol and methanol during SILAR, results in remarkably photoactive 3D heterostructure and recorded photocurrents were 44 times higher compared to bare titania nanotubes.
View Article and Find Full Text PDFPhotoenzyme Coupling System: Covalent Organic Frameworks In Situ Production of Hydrogen Peroxide Cascaded with Unspecific Peroxygenase to Achieve C-H Bonds Selective Activation.
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China.
As an efficient, sustainable, and environmentally friendly semiconductor material, covalent organic frameworks (COFs) can generate hydrogen peroxide (HO) by photocatalysis, attracting wide attention in recent years. Herein, the effects of hydroxyl, methoxyl, and vinyl groups of imide-linked two-dimensional (2D) COFs on the photocatalytic production of HO were studied theoretically and experimentally. The introduction of vinyl groups greatly promotes the photogenerated charge separation and migration of COFs, providing more oxygen adsorption sites, stronger proton affinity, and lower intermediate binding energy, which effectively facilitates the rapid conversion of oxygen to HO.
View Article and Find Full Text PDFThe use of green synthesized TiO/MnO nanoparticles in solar power membranes for pulp and paper industry wastewater treatment.
Sci Rep
January 2025
Physics Department, Faculty of Science, Cairo University, Giza, 12613, Egypt.
The pulp and paper manufacturing wastewater is as complicated as any other industrial effluent. A promising approach to treating water is to combine photocatalysis and membrane processes. This paper demonstrates a novel photocatalytic membrane technique for solar-powered water filtration.
View Article and Find Full Text PDFSynthesis of a three-phase heterojunction NdVO/VO/BiVO by cation exchange method for the degradation of anionic azo dye orange II.
Dalton Trans
January 2025
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, P.R. China.
Photocatalytic degradation of the azo dye orange II using NdVO/VO/BiVO under visible light is reported here, and this oxygen-rich defect three-phase heterojunction structure is constructed using a two-step cation exchange method. This heterojunction significantly enhances the separation and migration efficiency of photo-induced charges, while the accompanying oxygen defects effectively capture photogenerated electrons, thereby suppressing the recombination of electrons and holes. Experimental characterization and theoretical calculations demonstrate the efficient separation and transfer capabilities of photogenerated carriers and their excellent photocatalytic degradation performance.
View Article and Find Full Text PDFSynchronous Photocatalytic Redox Conversion of Chromium(VI) and Arsenic(III) by Bimetallic Fe/Ti Metal-Organic Frameworks.
Inorg Chem
January 2025
School of Life and Environmental Sciences, Shaoxing University, Huancheng West Road 508, Shaoxing 312000, P.R. China.
In this work, bimetallic organic frameworks NH-MOFs(Fe, Ti) with different Fe/Ti molar ratios were prepared by a hydrothermal method for the synchronous redox transformation of Cr(VI) and As(III). These results showed that NH-MIL-125(Ti) was less effective in the photocatalytic removal of Cr(VI), whereas NH-MIL-88B(Fe) was less effective in the photocatalytic oxidative removal of As(III). Due to the introduction of Fe, the photocatalytic reduction removal of Cr(VI) (23.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!