We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm (STP) cm at 298 K and 5-80 bar.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7953312 | PMC |
http://dx.doi.org/10.1039/c9cc06239d | DOI Listing |
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