Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.

Chem Commun (Camb)

State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China.

Published: September 2019

We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm (STP) cm at 298 K and 5-80 bar.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC7953312PMC
http://dx.doi.org/10.1039/c9cc06239dDOI Listing

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