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In situ growth of Fe(ii)-MOF-74 nanoarrays on nickel foam as an efficient electrocatalytic electrode for water oxidation: a mechanistic study on valence engineering. | LitMetric
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In situ growth of Fe(ii)-MOF-74 nanoarrays on nickel foam as an efficient electrocatalytic electrode for water oxidation: a mechanistic study on valence engineering.

Qijun Wang Feifei Wei Devaraj Manoj Zheye Zhang Junwu Xiao Xuezhu Zhao Fei Xiao Hairen Wang Shuai Wang

Chem Commun (Camb)

School of Chemistry and Chemical Engineering, Huazhong University of Science & Technology, Wuhan, 430074, P. R. China.

Published: September 2019

In this work, our theoretical results first demonstrate that varying the metal valence in MOFs plays a significant role in tuning their stable intrinsic electronic structure. Different valence Fe(ii) and Fe(iii) based pristine MOF-74 nanoarrays on nickel foam are further synthesized as electrodes for highly efficient electrocatalytic water oxidation.

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 Source
http://dx.doi.org/10.1039/c9cc05087fDOI Listing

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