Isothermal adsorption of polyampholytes on charged nanopatterned surfaces.

J Chem Phys

Instituto de Física, Universidade Federal do Rio Grande do Sul, Caixa Postal 15051, CEP 91501-970, Porto Alegre, RS, Brazil.

Published: August 2019

AI Article Synopsis

  • This research explores how neutral polyampholytes attach to surfaces that have charged areas but are overall neutral.
  • The study utilizes a combination of explicit interaction potentials and a 3D Ewald summation technique for efficient simulations.
  • Results show that the adsorption level and structure of polyampholytes are significantly influenced by surface patterns, the size of the charged domains, and the charge distribution on the polyampholyte backbone.

Article Abstract

We investigate the adsorption of neutral polyampholytes on charged nanopatterned surfaces. The surfaces have charged domains but are overall neutral. To perform efficient simulations, we use an approach which combines the explicit form of the interaction potential between the polyampholyte monomers and the surface with a 3d Ewald summation method. We observe that the amount of adsorption and the structure of the adsorbed polyampholytes depend strongly on the surface pattern, the relative size of the surface domains, and the charge distribution along the polyampholyte backbone.

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Source
http://dx.doi.org/10.1063/1.5115404DOI Listing

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