This experimental study investigated the utility of a pitch-based carbon fiber-mortar composite, which could replace polyacrylonitrile carbon fiber, as a thin overlay for concrete pavement. The objective was to explore the utility of the low-cost carbon fiber, which was produced via a melt-blown method, i.e., blowing at high pressure after melting the pitch residue following crude oil purification. The mechanical properties, durability, and thermal properties of the pitch-based carbon fiber were explored to maximize strength, durability, functionality, and economy by using micro-sized fibers that are closer in size to the constituents of cementitious materials. Melt-blown pitch-based carbon fiber has low individual fiber strength but generally excellent thermal conductivity. Thermal conductivity tests were conducted on mortar panels (560 mm × 560 mm; thickness = 25, 40 or 60 mm) containing 0, 0.4, 0.5 or 0.6 wt % pitch-based carbon fiber. The absolute thermal conductivity tended to improve with higher wt % of pitch-based carbon fiber, in the range of 9~11 W/°C. However, thermal conductivity tended to be lower under the 0.6 wt % condition, possibly due to the effect of dispersion. Compressive strength degradation was tested over 350 cycles of freezing and thawing: the strength of the 0.4, 0.5 or 0.6 wt % samples was 91, 89, and 82%, respectively, relative to the control specimen (0 wt %). Thus, all specimens had a compressive strength of 80% or more after 350 cycles compared to the control specimen. To test the adhesion performance for new thin overlays and old concrete surfaces, concrete cylinders (100 × 200 mm; thickness = 10 mm) were cut at an angle of 46 degrees, and the pitch-based carbon fiber-mortar composite was used to bond the various sections. The bond strength of the test specimens was more than twice that of the reference specimen.
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http://dx.doi.org/10.3390/ma12172753 | DOI Listing |
ACS Omega
November 2024
State Key Laboratory of Advanced Design and Manufacturing Technology for Vehicle, Hunan University, Changsha 410082, China.
Saturate (Sa), the lightest component in fluid catalytic cracking (FCC) slurry oil, exhibits a poorly understood influence on the formation and development of mesophase, thereby constraining the production of premium-quality mesophase pitch. To address this issue, Sa is isolated from FCC slurry oil, and its concentration is modulated to investigate its impact on the formation and development of mesophase. The results indicate that Sa contains a high concentration of long alkane side chains and naphthenic structures, which render it an effective "lubricant" and "activator" within the reaction system.
View Article and Find Full Text PDFLangmuir
December 2024
School of Resources and Environment, Northeast Agricultural University, Harbin 150030, China.
A coal tar pitch-based porous carbon adsorbent (CPA) was synthesized through a straightforward method involving the heating of a mixture of KOH and coal tar pitch (CTP). This CPA exhibited a high surface area of 1811.2 m g and a large pore volume of 0.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, PR China.
The development of advanced anode materials for sodium-ion batteries (SIBs) using pitch-based carbon materials has the advantages of low cost, high electrical conductivity and easy structural modification. In this research, various well-established modification techniques for petroleum pitch are integrated, including the use of recrystallized NaCl as molten salt template, pretreatment and high-temperature carbonization under a pure oxygen atmosphere, and the introduction of heteroatoms (N and S) by hydrothermal methods. The resulting two-dimensional carbon nanosheets with multielement modification exhibit enhanced Na storage properties, thereby bringing higher cycling stability and superior rate performance.
View Article and Find Full Text PDFNanomaterials (Basel)
August 2024
College of Energy and Power Engineering, North University of China, Taiyuan 030051, China.
Coal tar pitch (CTP) has become an ideal choice in the preparation of anode precursors for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) because of its abundant carbon content, competitive pricing and adjustable structure properties. In this paper, sulfurized pitch-based carbon (SPC-800) was obtained by allowing CTP to react with sulfur at 350 °C and subsequently achieve carbonization at 800 °C. SPC-800 was more disordered and had a larger layer spacing than carbonized CTP (PC-800).
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Sciences & Institute for Sustainable Energy, Shanghai University, Shanghai 200444, China. Electronic address:
Hard carbons derived from pitch are considered a competitive low-cost anode for sodium-ion batteries. However, the preparation of pitch-based hard carbon (PHC) requires the aid of a pre-oxidation strategy, which introduces unnecessary defects and oxygen elements, which leads to low initial Coulombic efficiency (ICE) and poor cycling stability. Herein, we demonstrate a new surface engineering strategy by grafting chemically active glucose molecules on the PHC surface via esterification reactions, which can achieve low-cost nano-scaled carbon coating.
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