Ecological awareness brought adequate innovations in the corrosion prevention technology in the last decade. Plant extracts are an interesting category among them, being the rich source of phytochemicals explored as corrosion inhibitors in various electrolytic media instead of toxic synthetic materials. Herein, the most ample tropical plant L. leaf (MIL) extract was prepared, and its antioxidant ability has been utilized for corrosion prevention of commercial steel in 3.5 wt % NaCl environment. A rich source of polyphenol content provided excellent anticorrosive property. Corrosion prevention occurs by forming an insoluble organometallic complex between metal ions and functional groups in the antioxidants at the metal-electrolyte interface. A new simple strategy is adopted here to make bio-extract containing epoxy coating on steel. An MIL-precipitated amorphous silica hybrid is incorporated in epoxy coating. Electrochemical measurement demonstrated that the developed coating has a superlative corrosion inhibition efficiency of 99%. Thus, the present findings demonstrate a novel environmentally benign, efficient corrosion inhibitor for steel protection in saline media.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6648491 | PMC |
http://dx.doi.org/10.1021/acsomega.9b00632 | DOI Listing |
Sci Rep
January 2025
Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, 574146, India.
Newly synthesized 1-bromo-2-(4-bromophenylsulfonate)-4,4-dimethyl-1-cyclohexenyl-6-one (CHD) as a potential anticorrosive agent in an acidic medium at an elevated temperature range of 305-335 K. This synthesized compound confirmed by spectral characterizations and it acts as a coating on mild steel surfaces in 1 M Hydrochloric acid (HCl) solution through electrochemical reactions. The synthesis of the compound has been discussed, and the Infrared (IR) and Nucleic Magnetic Resonance (NMR) spectral analysis confirmed the derivative.
View Article and Find Full Text PDFSci Rep
December 2024
Civil Engineering Department, Shoolini University, Solan, Himachal Pradesh, 173229, India.
Geopolymer concrete (GPC) offers a sustainable alternative by eliminating the need for cement, thereby reducing carbon dioxide emissions. Using durable concrete helps prevent the corrosion of reinforcing bars and reduces spalling caused by chemical attacks. This study investigates the impact of adding 5, 10, and 15% silica fumes (SF) on the mechanical and durability properties of GPC cured at 60 °C for 24 h.
View Article and Find Full Text PDFEnviron Res
December 2024
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China. Electronic address:
Photocatalytic antibacterial technology has the potential to prevent the formation of biofilms and microbial corrosion of metals by rapidly eliminating microorganisms in a short period. In this study, novel NH-MIL-101(Al)/AgI is in-situ synthesized at ambient temperature, revealing enhanced photocatalytic antibacterial activity and cyclic stability in seawater. A low dosage of 0.
View Article and Find Full Text PDFMed J Armed Forces India
December 2024
Associate Professor (Forensic Medicine), Agartala Government Medical College, Tripura, India.
Background: Rubber latex processing acid poisoning is a frequently encountered phenomenon in Tripura. Formic acid is the preferred choice for coagulating rubber latex in rubber sheet manufacturing units. The objective of this study aimed to assess the epidemiological profile of poisoning deaths by rubber processing acid and to record their autopsy findings.
View Article and Find Full Text PDFNanotechnology
December 2024
Department of Chemistry, Pandit Deendayal Energy University, Raysan, Gandhinagar, Gujarat, 382426, INDIA.
MXenes (two-dimensional (2D) transition-metal carbides, nitrides, and carbonitrides) are gaining significant interest as alternative electrocatalysts for the hydrogen evolution reaction due to their excellent properties, such as high electrical conductivity, large surface area, and chemical stability. MXenes are traditionally synthesized using hydrofluoric acid (HF), which raises safety and environmental concerns due to its highly corrosive and toxic nature. HF introduces fluoride functional groups on the surface of MXenes, which have been reported to have a detrimental effect on electrocatalysis.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!