The selective separation of ethanol/acetonitrile by porous materials has rarely been observed owing to their similar physicochemical properties. In this work, we report a new coordination network, [Cu(4-pmntd)(opd)](4-pmntd = ,'-bis(4-pyridymethy)naphthalene diimide, opd = disodium 1,2-benzenedicarboxylate), which exhibits selective separation of ethanol over acetonitrile. The weak coordination bonds formed by unsaturated Cu sites and hydroxyl groups are the key to such performance.
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| http://dx.doi.org/10.1021/acsomega.8b03229 | DOI Listing |
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