Hydration and Hydroxylation of MgO in Solution: NMR Identification of Proton-Containing Intermediate Phases.

Magnesium oxide (MgO)-engineered barriers used in subsurface applications will be exposed to high concentration brine environments and may form stable intermediate phases that can alter the effectiveness of the barrier. To explore the formation of these secondary intermediate phases, MgO was aged in water and three different brine solutions and characterized with X-ray diffraction (XRD) and H magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy. After aging, there is ∼4% molar equivalent of a hydrogen-containing species formed. The H MAS NMR spectra resolved multiple minor phases not visible in XRD, indicating that diverse disordered proton-containing environments are present in addition to crystalline Mg(OH) brucite. Density functional theory (DFT) simulations for the proposed Mg-O-H-, Mg-Cl-O-H-, and Na-O-H-containing phases were performed to index resonances observed in the experimental H MAS NMR spectra. Although the intermediate crystal structures exhibited overlapping H NMR resonances in the spectra, Mg-O-H intermediates were attributed to the growth of resonances in the δ +1.0 to 0.0 ppm region, and Mg-Cl-O-H structures produced the increasing contributions of the δ = +2.5 to 5.0 ppm resonances in the chloride-containing brines. Overall, H NMR analysis of aged MgO indicates the formation of a wide range of possible intermediate structures that cannot be observed or resolved in the XRD analysis.