The access to free, unsolvated ions at high concentrations and ambient temperatures enabled by ionic liquids results in previously unobserved reactivity for even well-studied ions, demonstrated here by acetate ([OAc]) acting as a reducing agent for BH but only when used as a neat liquid in [Cmim][OAc] at ambient temperature. More typical reaction products are obtained when BH is reacted with [Cmim][OAc] at an elevated temperature or in the presence of strong bases.
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| http://dx.doi.org/10.1021/acsomega.8b00775 | DOI Listing |
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