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Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide. | LitMetric

Rationally Designed Circularly Arranged Sextuple Molecule with Dimethoxyphenolic Tentacles for Ample Hunting of Cyanide.

ACS Omega

UGC Sponsored Centre for Advanced Studies, Department of Chemistry, Guru Nanak Dev University, Amritsar 143005, India.

Published: July 2018

AI Article Synopsis

Article Abstract

Herein, we report the design, synthesis, and cyanide-scavenging behavior of circularly arranged sextuple molecule 4. The six syringaldehyde units carrying equal number of dimethoxyphenolic moieties projecting at the periphery make the molecule highly efficient for cleaning up cyanide from the aqueous solution. The stoichiometric data 1:6 showed that six units of cyanide interact with one unit of compound 4. The association constant of the compound for cyanide was 2.5 × 10 M, and its detection limit for cyanide was 10 nM. The compound was also found to remove cyanide bound to cytochrome oxidase.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6644536PMC
http://dx.doi.org/10.1021/acsomega.8b01155DOI Listing

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