Versatile Approach for Reducing Propagation Loss in Wet-Electrospun Polymer Fiber Waveguides.

Wet-electrospun (WES) polymer micron and submicron fibers are promising building blocks for small, flexible optical fiber devices, such as waveguides, sensors, and lasers. WES polymer fibers have an inherent cylindrical geometry similar to that of optical fibers and a relatively large aspect ratio. Furthermore, WES fibers can be produced using low-cost and low-energy manufacturing techniques with large-area fabrication and a large variety of materials. However, the high propagation loss in the fibers, which is normally on the order of tens or thousands of decibels per centimeter in the visible light region, has impeded the use of these fibers in optical fiber devices. Here, the origin of propagation losses is examined to develop a comprehensive and versatile approach to reduce these losses. The excess light scattering that occurs in fibers due to their inhomogeneous density is one of the primary factors in the propagation loss. To reduce this loss, the light transmission characteristics were investigated for single WES polymer fibers heated at different temperatures. The propagation loss was significantly reduced from 17.0 to 8.1 dB cm at 533 nm wavelength, by heating the fibers above their glass transition temperature, 49.8 °C. In addition, systematic verification of the possible loss factors in the fibers confirmed that the propagation loss reduction could be attributed to the reduction of extrinsic excess scattering loss. Heating WES polymer fibers above their glass transition temperature is a versatile approach for reducing the propagation loss and should be applicable to a variety of WES fibers. This finding paves the way for low-loss WES fiber waveguides and their subsequent application in small, flexible optical fiber devices, including waveguides, sensors, and lasers.