A new family of iodoplumbates based on phosphonium cations have been synthesized and characterized via X-ray crystallography. Thermogravimetric analysis demonstrates that these materials have a remarkably high thermal stability and show potential for applications as organic-inorganic hybrid semiconductors. We also present the synthesis of three novel phosphonium salts and the crystallographic elucidation of these compounds.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6643556 | PMC |
| http://dx.doi.org/10.1021/acsomega.8b02240 | DOI Listing |
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Phosphonium-Templated Iodoplumbates.
ACS Omega
December 2018
Department of Chemistry and Biochemistry, University of Windsor, 401 Sunset Avenue, Windsor, Ontario, Canada N9B 3P4.
A new family of iodoplumbates based on phosphonium cations have been synthesized and characterized via X-ray crystallography. Thermogravimetric analysis demonstrates that these materials have a remarkably high thermal stability and show potential for applications as organic-inorganic hybrid semiconductors. We also present the synthesis of three novel phosphonium salts and the crystallographic elucidation of these compounds.
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