We present the physics of sequential dewetting phenomenon and continuous fabrication of a polymeric microstencil using dewetting phenomenon with roll-to-roll imprinting equipment. To realize dewetting-assisted residual-free imprinting, mold material, polymer resin, and substrate were selected via interfacial surface energy analysis. In addition, optimal parameters of the continuous process were also studied by experimentally comparing the resultant shape of the microstencil depending on the process speed, aspect ratio of the mold, and applied pressure. As a result, the polymeric microstencil was produced continuously in very high yields, and its maximum resolution reached 20 μm in diameter. For an easy, continuous demolding during the roll-to-roll process, the material chosen for the substrate film was paraffin-coated film, which has the surface energy low enough for dewetting while having a higher adhesion value than polydimethylsiloxane mold. This versatile, high-throughput microstencil fabrication process can be used in many applications requiring flexibility, scalability, and specific material, and high productivity.
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http://dx.doi.org/10.1021/acsomega.7b00070 | DOI Listing |
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December 2024
School of Materials Science and Engineering, Tongji University, Shanghai, 201804, China.
Liquid metals (LMs), as an emerging group of functional materials, possess the necessary conditions for dewetting. However, LM dewetting garnered grossly inadequate attention. Here, an intriguing phenomenon termed active corrosion-triggered dewetting (ACT-Dewetting) of LMs is reported.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
New Cornerstone Science Laboratory, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, Anhui Engineering Laboratory of Biomimetic Materials, Division of Nanomaterials and Chemistry, Hefei National Research Center for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China.
Plateau-Rayleigh instability─a macroscopic phenomenon describing the volume-constant breakup of one-dimensional continuous fluids─has now been widely observed in adatoms, liquids, polymers, and liquid metals. This instability enables controlled wetting-dewetting behavior at fluid-solid interfaces and, thereby, the self-limited patterning into ordered structures. However, it has yet to be observed in conventional inorganic solids, as the rigid lattices restrict their "fluidity".
View Article and Find Full Text PDFACS Polym Au
August 2024
Soft and Biological Matter Laboratory, Department of Physics, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Pattern formation during solution evaporation is common in several industrial settings and involves a complex interplay of multiple processes, including wetting/dewetting, diffusion, and rheological characteristics of the solution. Monitoring the emergence of patterns during evaporation under controlled conditions may allow deconvolution of different processes and, in turn, improve our understanding of this common yet complex phenomenon. Here, we probe the importance of initial conditions, defined by the solution concentration , on the pattern formation in evaporating polymer solutions on the air-water interface.
View Article and Find Full Text PDFLangmuir
July 2024
Stuttgart Laboratory 2, Sony Europe B.V., Hedelfinger Strasse 61, Stuttgart D-70327, Germany.
Water dewetting generates static electricity. We reviewed historical experiments of this phenomenon, and we studied the charging of polymer slides and metal electrode supported polymer films withdrawn vertically from a pool of aqueous solutions. For pure water, charging was negative and surface charge densities increased with the speed of dewetting, which we explain by the thermally activated entrainment of nanometer-sized water droplets or clusters charged by unbalanced adsorbed electric double-layer ions.
View Article and Find Full Text PDFACS Appl Mater Interfaces
July 2024
Lab of Soft Interfaces, Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology Bombay, Mumbai 400076, India.
We demonstrate a simple droplet diagnostic approach to monitor the UiO-66 MOF (metal-organic framework) synthesis and its quality using the sessile droplet drying phenomenon. Drying a sessile droplet involves evaporation-driven hydrodynamic flow and particle-nature-dependent self-assembled deposition. In general, the MOF synthesis process involves different sizes and physicochemical nature of particles in every synthesis stage.
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