Some large-scale testing requires examinees to select and answer a fixed number of items from given items (e.g., select one out of the three items). Usually, they are constructed-response items that are marked by human raters. In this examinee-selected item (ESI) design, some examinees may benefit more than others from choosing easier items to answer, and so the missing data induced by the design become missing not at random (MNAR). Although item response theory (IRT) models have recently been developed to account for MNAR data in the ESI design, they do not consider the rater effect; thus, their utility is seriously restricted. In this study, two methods are developed: the first one is a new IRT model to account for both MNAR data and rater severity simultaneously, and the second one adapts conditional maximum likelihood estimation and pairwise estimation methods to the ESI design with the rater effect. A series of simulations was then conducted to compare their performance with those of conventional IRT models that ignored MNAR data or rater severity. The results indicated a good parameter recovery for the new model. The conditional maximum likelihood estimation and pairwise estimation methods were applicable when the Rasch models fit the data, but the conventional IRT models yielded biased parameter estimates. An empirical example was given to illustrate these new initiatives.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6696873 | PMC |
http://dx.doi.org/10.1177/0146621618798667 | DOI Listing |
J Food Sci
December 2024
Department of Food and Agricultural Product Technology, Faculty of Agricultural Technology, Gadjah mada University, Yogyakarta, Indonesia.
JACS Au
December 2024
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China.
The chemical similarities between trivalent actinides [An(III)] and lanthanides [Ln(III)] present a significant challenge in differentiating and separating them, which is a key step toward closing the nuclear fuel cycle. However, the existing separation approaches commonly suffer from demerits such as inadequate separation factors, limited stripping efficiency, and undesired coextraction. In this study, a novel unsymmetrical phenanthroline-derived amide-triazine (Et-Tol-CyMe-ATPhen) extractant was first designed and then screened with theoretical computation.
View Article and Find Full Text PDFJACS Au
December 2024
Department of Chemistry, University of Puerto Rico, Río Piedras Campus, Río Piedras, Puerto Rico 00931, United States.
Targeting iron metabolism has emerged as a novel therapeutic strategy for the treatment of cancer. As such, iron chelator drugs are repurposed or specifically designed as anticancer agents. Two important chelators, deferasirox (Def) and triapine (Trp), attack the intracellular supply of iron (Fe) and inhibit Fe-dependent pathways responsible for cellular proliferation and metastasis.
View Article and Find Full Text PDFChemosphere
December 2024
São Carlos Institute of Chemistry, University of São Paulo, Avenida Trabalhador São Carlense, 400, São Carlos, 13566-590, Brazil. Electronic address:
The present work investigated the application of UVC combined with electrogenerated HO (UVC/e-HO) for BTA degradation using a Printex L6 carbon-based (PL6C) gas diffusion electrode (GDE). The studies were carried out by analyzing the influence of the current density, pH and initial BTA concentration in the contaminant degradation process. Under optimal conditions using 0.
View Article and Find Full Text PDFSe Pu
January 2025
West China School of Pharmacy, Sichuan University, Chengdu 610041, China.
Ambient mass spectrometry imaging (MSI) enables hundreds of analytes in tissue sections to be directly mapped at atmospheric pressure with minimal sample preparation. This field is currently experiencing rapid growth, with numerous reported ambient ionization techniques resulting in a "hundred flowers bloom" situation. Nanospray desorption electrospray ionization (nano-DESI), developed by the Laskin group in 2010, is a widely used liquid-extraction-based ambient ionization technique that was first used for mass spectrometry imaging of tissue in 2012.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!