Copper nanowires (CuNWs) are used to prepare flexible, transparent conducting substrates due to their low cost and ease of fabrication on a large area. A CuNW/polymer composite substrate was prepared and vulcanized to create a novel flexible nano-CuS/polymer composite substrate. The physical and photovoltaic properties of the substrate can be controlled by tuning the concentration of CuNW dispersion during the preparation of CuNWs and nano CuS films. The nano-CuS-based composite substrate was used as an effective flexible counter electrode of a quantum-dot-sensitized solar cell (QDSSC) and resulted in a maximum cell efficiency of 1.01%.
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http://dx.doi.org/10.1038/s41598-019-48809-7 | DOI Listing |
Chem Commun (Camb)
January 2025
Graphene Composite Research Center, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, 518060, P. R. China.
In this study, a distinctive multiple core-shell structure of Co nanoparticles inserted into N-doped carbon dodecahedron@Co hydroxide (Co/NCD@Co(OH)) was synthesized a spontaneous redox reaction between metallic Co and NO, ultimately materializing the fine dispersion and exposure of the active sites. The electronic interaction existing between the Co/NCD core and the Co(OH) shell brings a synergistic effect, conspicuously lessens the overpotential, and reinforces the yield-rate and faradaic efficiency of NH for electrochemical nitrate-ammonia conversion. This study underlines the spontaneous redox between the catalysts and substrate, rendering it as a synthetic strategy for designing genuine and well-dispersed active sites.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, 110016, P. R. China.
It is a major challenge to obtain broadband microwave absorption (MA) properties using low dielectric or magnetic nanoparticle-decorated carbon composites due to the limited single conductive loss or polarization loss of the carbon materials used as substrates. Novel pure cellulose-derived graphite carbon (CGC) materials can be used as an exceptional substrate option due to their special defective graphitic carbon structure, which provides both conduction and polarization loss. Herein, CGC@ZnO composites were first synthesized by atomic layer deposition (ALD) for use as microwave absorbents.
View Article and Find Full Text PDFHerein, a novel magnetic resorcinol-formaldehyde-supported isatin-Schiff-base/Fe complex (FeO@RF-ISB/Fe) is prepared and characterized and its catalytic performance is investigated in the synthesis of pyrano[2,3-]pyrimidines. The FeO@RF-ISB nanomaterial was prepared through the chemical immobilization of (3-aminopropyl)trimethoxysilane over the FeO@RF composite, followed by treatment with isatin. The FeO@RF-ISB was then reacted with FeCl·6HO to afford the FeO@RF-ISB/Fe nanocatalyst.
View Article and Find Full Text PDFInt J Obes (Lond)
January 2025
Department of Health, Kinesiology, and Applied Physiology, Concordia University, Montreal, QC, Canada.
Objective: Compared to adulthood-onset obesity (AO), those with childhood-onset obesity (CO) are at greater risk of metabolic disease. However, the differences between these two obesity phenotypes are not clear. The aim of this study is to investigate how the age of obesity onset (CO vs.
View Article and Find Full Text PDFLasers Med Sci
January 2025
Department of Preventive and Restorative Dentistry, Discipline of Endodontics, Araçatuba School of Dentistry, São Paulo State University - UNESP, Araçatuba, SP, Brazil.
Investigate the impact of antimicrobial photodynamic therapy (aPDT) using different photosensitizers (PSs) such as indocyanine green (IG), curcumin (CC), and methylene blue (MB), with or without intracanal application of calcium hydroxide (CH), on the push-out bond strength of glass-fiber posts (GFPs) to intraradicular dentin, the chemical composition of the root substrate, and the sealing of the adhesive interface across different thirds of intraradicular dentin. A total of 112 bovine teeth underwent biomechanical preparation and were divided into eight experimental groups (n = 14 each): Negative control with deionized water; positive control with deionized water + CH; IG group with indocyanine green and infrared laser; IG + CH group; CC group with curcumin and blue LED; CC + CH group; MB group with methylene blue and red laser; and MB + CH group. The push-out bond strength was measured using a universal testing machine (n = 8), and scanning electron microscopy characterized the fracture patterns.
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