The remotion of hexavalent chromium in the form of chromate in aqueous solution was done using the aquatic plant Salvinia sp as biosorbent. The chemical modification of the Salvinia surface was performed by organosolv adapted method. The untreated Salvinia and the modified were characterized by infrared spectroscopy, Boehm titration, scanning electron microscopy, energy dispersive system, point of zero charge, surface area analysis, and porosity. Batch adsorption experiments were performed to observe the effects of pH, contact time, initial concentration, and temperature on the metal removal process. The characterization results show the chemistry modifically changed the modified Salvinia structure compared with untreated Salvinia. The adsorption test results showed the maximum adsorption capacity of 26.03 mg g. The kinetic equilibrium was reached in about 3 h, and the better temperature and pH were 298 K and 7, respectively. The adsorption and kinetic models were Freundlich and pseud-second order, respectively. This study showed the Salvinia sp after the chemical treatment can be used with biosorbent for hexavalent chromate in the form of chromate, being a natural material with low cost and plentiful in the environment.
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http://dx.doi.org/10.1007/s11356-019-06127-5 | DOI Listing |
Anal Chim Acta
November 2024
IFEG (Physics Institute Enrique Gaviola), CONICET (National Research Council Scientific and Technical) Córdoba, Argentina; Faculty of Mathematics, Physics, Astronomy and Computation. National University of Córdoba. Córdoba, Argentina. Electronic address:
Background: Remediation of heavy metal-contaminated water using phytoremediation with accumulator aquatic plants is a promising low-cost emerging technology that adapts very well to the surrounding ecosystem. For the system to work efficiently, metal-saturated plants must be replaced, producing a potentially toxic amount of biomass that is usually stored dry to reduce its volume. The speciation of the high metal content in this biomass is crucial to define its final destination.
View Article and Find Full Text PDFInt J Phytoremediation
October 2024
Plant Physiology, Biochemistry and Plant Molecular Biology Research Unit, Department of Botany, University of Kalyani, Kalyani, West Bengal, India.
Methylene blue, a cationic dye as a pollutant is discharged from industrial effluent into aquatic bodies. The dye is biomagnified through the food chain and is detrimental to the sustainability of aquatic flora. Despite of number of physico-chemical techniques of dye removal, the use of aquatic flora for bio-adsorption is encouraged.
View Article and Find Full Text PDFEnviron Pollut
April 2024
College of Chemistry and Bioengineering, Hunan University of Science and Engineering, 425199, Yongzhou, Hunan, China. Electronic address:
Coconut shell activated carbon (CNSAC) was applied as a filter layer in hybrid vertical subsurface flow constructed wetland (H-VSSF-CW), in order to enhance the multi-metal removal efficiency of the constructed wetland (CW) and to reduce heavy metal accumulation on Salvinia cucullata. Treatment P + AC, (having CNSAC filter layer), showed 32, 21 and 34% more Cd, Cr, and Pb removal efficiency than treatment P (without CNSAC layer). CNSAC activated carbon adsorbed Cd and Pb and Cr by functional groups -NH, -NO2, -C-O, -OH and -CO, and significantly reduced Cd and Pb exposure to S.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2023
Department of Environmental Sciences, Maharshi Dayanand University, Rohtak, Haryana, 124001, India.
Nanocomposite adsorbents for wastewater treatment gained popularity in recent times. In the present study, nanoparticles prepared from lanthanum have been loaded on the powdered form of aquatic plants Salvinia molesta (S. molesta) and Typha latifolia (T.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2023
Department of Chemistry, St. Joseph's Institute of Technology, 600 119, Chennai, India.
The present investigation provides a kinetic study for the removal of hexamethyl pararosaniline chloride, a hazardous dye, by phytoremediation using a water plant. It reveals Salvinia molesta has a phytoremediation tendency. The ability of Salvinia molesta to remove crystal violet (CV) dye is investigated with kinetic study in this research.
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