The exquisite optical and spin properties of nitrogen-vacancy (NV) centers in diamond have made them a promising platform for quantum sensing. The prospect of NV-based sensors relies on the controlled production of these atomic-scale defects. Here we report on the fabrication of a preferentially oriented, shallow ensemble of NV centers and their applicability for sensing dc magnetic fields. For the present sample, the residual paramagnetic impurities are the dominant source of environmental noise, limiting the dephasing time (T) of the NVs. By controlling the P1 spin-bath, we achieve a 4-fold improvement in the T of the NV ensemble. Further, we show that combining spin-bath control and homonuclear decoupling sequence cancels NV-NV interactions and partially protects the sensors from a broader spin environment, thus extending the ensemble T up to 10 μs. With this decoupling protocol, we measure an improved dc magnetic field sensitivity of 1.2 nT μm Hz. Using engineered NVs and decoupling protocols, we demonstrate the prospects of harnessing the full potential of NV-based ensemble magnetometry.
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Sci Rep
January 2025
Laboratory of Functional and Molecular Imaging, National Institute of Neurological Disorders and Stroke, National Institutes of Health, Bethesda, MD, 20892, USA.
In a step towards generating switchable MRI cellular labels, we demonstrate in-situ field switching of micron scale metamagnetic Iron-Rhodium (FeRh) thin film particles. A thin-film (200 nm) FeRh sample was fabricated and patterned into an array of progressively smaller squares with sizes ranging from 500 μm down to 1 μm. The large first order phase change from antiferromagnetic to ferromagnetic state was characterized using vibrating sample magnetometry, magnetic force microscopy, and MRI.
View Article and Find Full Text PDFNano Lett
January 2025
Max Planck Institute for Solid State Research, Heisenbergstr. 1, Stuttgart, 70569, Germany.
Spin Hall nano-oscillators convert DC to magnetic auto-oscillations in the microwave regime. Current research on these devices is dedicated to creating next-generation energy-efficient hardware for communication technologies. Despite intensive research on magnetic auto-oscillations within the past decade, the nanoscale mapping of those dynamics remained a challenge.
View Article and Find Full Text PDFChemSusChem
January 2025
Swinburne University of Technology - Hawthorn Campus: Swinburne University of Technology, Chemistry and Biotechnology, AUSTRALIA.
The removal of heavy metal ions, such as lead (Pb2+), from aqueous systems is critical due to their high toxicity and bioaccumulation in living organisms. This study presents a straightforward approach for the synthesis and surface modification of iron oxide nanoparticles (IONPs) for the magnetic removal of Pb2+ ions. IONPs were produced via electrosynthesis at varying voltages (10-40 V), with optimal magnetic properties achieved at 40 V resulting in highly crystalline and magnetic IONPs in the gamma-maghemite (γ-Fe2O3) phase.
View Article and Find Full Text PDFPLoS Biol
January 2025
Neuroscience Institute, New York University Grossman School of Medicine, New York, New York, United States of America.
Perceptual awareness results from an intricate interaction between external sensory input and the brain's spontaneous activity. Pre-stimulus ongoing activity influencing conscious perception includes both brain oscillations in the alpha (7 to 14 Hz) and beta (14 to 30 Hz) frequency ranges and aperiodic activity in the slow cortical potential (SCP, <5 Hz) range. However, whether brain oscillations and SCPs independently influence conscious perception or do so through shared mechanisms remains unknown.
View Article and Find Full Text PDFNano Lett
January 2025
Materials Science and Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Rd, Oak Ridge, Tennessee 37831, United States.
Thermally driven transitions between ferromagnetic and paramagnetic phases are characterized by critical behavior with divergent susceptibilities, long-range correlations, and spin dynamics that can span kHz to GHz scales as the material approaches the critical temperature , but it has proven technically challenging to probe the relevant length and time scales with most conventional measurement techniques. In this study, we employ scanning nitrogen-vacancy center based magnetometry and relaxometry to reveal the critical behavior of a high- ferromagnetic oxide near its Curie temperature. Cluster analysis of the measured temperature-dependent nanoscale magnetic textures points to a 3D universality class with a correlation length that diverges near .
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