A simple process for extracting cellulose nanocrystals (CNCs) is proposed that only uses high-pressure homogenization (HPH) controlling a process temperature. The proposed process was assessed and compared with normal production through acidic hydrolysis. Temperature-controlled HPH produced CNCs with high crystallinity, which linearly increased with increasing process temperature over 20 passes. The CNCs had uniform widths and lengths in the ranges of 4-14 nm and 60-320 nm, respectively. Undesirable chemical reaction can be avoided with the proposed process because no chemical was used to promote the CNC extraction. This method is an efficient and sustainable green approach to CNC production.
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http://dx.doi.org/10.1016/j.carbpol.2019.115114 | DOI Listing |
Carbohydr Polym
March 2025
Department of Chemical Engineering, Waterloo Institute for Nanotechnology, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L 3G1, Canada. Electronic address:
Research on the interaction between surfactants and cellulose nanocrystals (CNC) has mainly focused on the interaction between CNC and conventional surfactants, and there are no reported studies on the interaction between CNC and gemini surfactants. The interactions between CNC and conventional surfactant (tetradecyltrimethylammonium bromide, termed as TTAB), asymmetric gemini surfactant ([CH(CH)N(CH)N(CH)CH]Br (14-6-6)) or symmetric gemini surfactant ([CH(CH)N(CH)N(CH)CH]Br (14-6-14)) were examined. With increasing surfactant concentration, interaction of TTAB/CNC was described by three regions, i.
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March 2025
Key Laboratory of Intelligent Textile and Flexible Interconnection of Zhejiang Province, Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
The environmental challenges linked to petroleum-based polymers have accelerated the search for alternative materials like polylactic acid (PLA). Diverse nanofillers, ranging from inorganic to organic and hybrid inorganic/organic varieties, are employed to bolster PLA performance. Yet, non-synergistic nanofillers often underperform due to inadequate dispersion and singular functionality within the PLA matrix.
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March 2025
Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, China. Electronic address:
Uncontrolled release of active agents in active packaging reduces antimicrobial efficacy, hindering the effective protection of perishable products from microbial infection. Herein, a novel defective engineering was proposed to design defective and hollow ZIF-8 structures grown on TEMPO oxidized cellulose nanofibrils (TOCNFs) and use them as fast-reacting nanocarriers for loading and controlled release curcumin (Cur) in sodium alginate (SA) active packaging systems (CZT-Cur-SA). By employing stable chelation between tannic acid (TA) and ZIF-8 zinc ions, the connections between zinc ions and imidazole ligands were severed to form a loose and hollow structure, which facilitates the rapid reaction and release of active ingredients triggered by pH changes in the microenvironment.
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Department of Polymer Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Republic of Korea. Electronic address:
The global challenge of wastewater contamination, especially from persistent pollutants like radioactive isotopes and heavy metals, demands innovative purification solutions. Radioactive iodine isotopes (I and I), stemming from nuclear activities, pose serious health risks due to their mobility, bioaccumulation, and ionizing radiation, particularly impacting thyroid health. Similarly, hexavalent chromium, Cr(VI), is highly toxic and persistent in water, linked to cancer and other severe health issues.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, PR China. Electronic address:
Multidirectional strain sensors are of technological importance for wearable devices and soft robots. Here, we report that flexible materials capable of multidirectional anisotropic strain sensing can be constructed leveraging diffusion-induced infiltration of monomers and in situ polymerization of metal ion-containing double network hydrogels in and on the surface of micro-corrugated chiral nematic cellulose nanocrystal/glucose films. Integrating the micro-corrugated cellulose nanocrystal/glucose chiral nematic films with ionic conductive hydrogels of PAA-co-AAm/sodium alginate/Al endows the materials with multidirectional mechanoelectrical resistivity and mechanochromism anisotropy.
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