Guar gum (GG) was investigated as a possible eco-friendly corrosion inhibitor for pure aluminium in a 1-M HCl solution at different temperatures and immersion times using gravimetric and electrochemical techniques. The results showed that GG was a good corrosion inhibitor for pure aluminium in the studied environment. The inhibition efficiency of GG increased with increasing inhibitor concentration and immersion time but decreased with increasing temperature. Polarisation measurements revealed that GG was a mixed type inhibitor with a higher influence on the cathodic reaction. The adsorption behaviour of the investigated inhibitor was found to obey the Temkin adsorption isotherm and the calculated values of the standard free adsorption energy indicate mixed-type adsorption, with the physical adsorption being more dominant. The associated activation energy () and the heat of adsorption () supported the physical adsorption nature of the inhibitor. Fourier-transform infrared spectroscopy (FTIR) and Raman/SERS were used to explain the adsorption interaction between the inhibitor with the surface of the metal. The results suggested that most inhibition action of GG is due to its adsorption of the metal surface via H-bond formation.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6720888 | PMC |
| http://dx.doi.org/10.3390/ma12162620 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Understanding 2-(Nitromethylene)hexahydropyrimidin-5-ol Reaction Processes and NMR Spectroscopy: A Theoretical and Experimental Investigation.
ACS Omega
January 2025
Departamento de Física - Instituto de Ciências Exatas - ICEx, Universidade Federal Fluminense, Volta Redonda, Rio de janeiro 27213-145,Brazil.
Ketene dithioacetals have significant applications in various fields, including natural products, pharmaceuticals, agrochemicals, and corrosion inhibitors. These compounds are highly valued for their reactivity and ability to participate in a wide range of organic syntheses. In this context, the reaction between 1,3-diaminopropan-2-ol and 1,1-bismethylsulfanyl-2-nitroethylene has been studied experimentally and theoretically by using density functional theory (DFT) calculations.
View Article and Find Full Text PDFA sustainable and green method for controlling acidic corrosion on mild steel using leaves of Araucaria heterophylla.
Sci Rep
January 2025
Faculty of Nano and Bio Science and Technology, Persian Gulf University, Bushehr, 75169, Iran.
There are several studies that announce the inhibitory behavior of this sort of substance to strengthen the shield of metals, which is one of the positive benefits of green inhibitors. In the current investigation, Araucaria heterophylla studied as a green corrosion inhibitor to avert the mild steel during the acidic cleaning. The examination of this plant's ability to control corrosion at different concentrations in the acidic solution used certain expert measures.
View Article and Find Full Text PDFSelf-Healing Superhydrophobic Coatings with Multiphase Repellence Property.
ACS Appl Mater Interfaces
January 2025
Centre for Advanced Laser Manufacturing (CALM), School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, P. R. China.
Developing versatile, scalable, and durable coatings that repel various matters in different service environments is of great importance for engineered materials applications but remains highly challenging. Here, the mesoporous silica microspheres (HMS) fabricated by the hard template method were utilized as micro-nanocontainers to encapsulate the hydrophobic agent of perfluorooctyltriethoxysilane (F13) and the corrosion inhibitor of benzotriazole (BTA), forming the functional microsphere of F-HMS(BTA). Moreover, the synthesized organosilane-modified silica sol adhesive (SMP) and F-HMS(BTA) were further employed as the binder and functional filler to construct a superhydrophobic self-healing coating of SMP@F-HMS(BTA) on various engineering metals through scalable spraying.
View Article and Find Full Text PDFSynthesis and evaluation of CuNi-MOF as a corrosion inhibitor of AISI 304 and 316 stainless steel in 1N HCl solution.
Heliyon
January 2025
Department of Materials Engineering, Isfahan University of Technology, Isfahan, 84156-83111, Iran.
A bimetallic organic framework (CuNi-MOF) was synthesized as a corrosion inhibitor using the solvothermal method. The effectiveness of the inhibitor in corrosion prevention of AISI 304 and 316 in 1N hydrochloric acid solution at room temperature was evaluated using weight loss measurements, electrochemical methods, and surface characterization techniques. The formation of CuNi-MOF protective layer on the stainless-steel surface was confirmed through Field Emission Scanning Electron Microscopes (FESEM), Energy Dispersive Spectroscopy (EDS), and X-Ray Diffraction (XRD) analysis.
View Article and Find Full Text PDFMitigating matrix effects in oil and gas wastewater analysis: LC-MS/MS method for ethanolamines.
Environ Sci Process Impacts
January 2025
Massachusetts Institute of Technology, Department of Civil and Environmental Engineering, Parsons Laboratory, 15 Vassar Street, Cambridge, Massachusetts 02139, USA.
The high salinity and organic content in oil and gas wastewaters can cause ion suppression during liquid chromatography mass spectrometry (LC/MS) analysis, diminishing the sensitivity and accuracy of measurements in available methods. This suppression is severe for low molecular weight organic compounds such as ethanolamines (, monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), -methyldiethanolamine (MDEA), and ,-ethyldiethanolamine (EDEA)). Here, we deployed solid phase extraction (SPE), mixed-mode LC, triple quadrupole MS with positive electrospray ionization (ESI), and a suite of stable isotope standards (, one per target compound) to correct for ion suppression by salts and organic matter, SPE losses, and instrument variability.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!