Rechargeable aqueous zinc-ion batteries (ZIBs) have garnered tremendous attention in the field of next energy storage devices due to their high safety, low cost, abundant resources, and eco-friendliness. As an important component of the zinc-ion battery, the electrolyte plays a vital role in the electrochemical properties, since it will provide a pathway for the migrations of the zinc ions between the cathode and anode, and determine the ionic conductivity, electrochemically stable potential window, and reaction mechanism. In this Minireview, a brief introduction of electrochemical principles of the aqueous ZIBs is discussed and the recent advances of various aqueous electrolytes for ZIBs, including liquid, gel, and multifunctional hydrogel electrolytes are also summarized. Furthermore, the remaining challenges and future directions of electrolytes in aqueous ZIBs are also discussed, which could provide clues for the following development.
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http://dx.doi.org/10.1002/chem.201902660 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherlands.
Chromium-based functional coatings (CFCs) are widely recognized for their outstanding wear and corrosion resistance across diverse industrial sectors. However, despite advancements in deposition techniques and microstructural enhancements, many contemporary CFCs remain vulnerable to degradation in highly corrosive environments. For the first time, this research delivers a thorough characterization of the corrosion resistance of advanced CFCs, focusing on the performance of a 5 μm thin dense chromium (TDC) coating.
View Article and Find Full Text PDFSmall
January 2025
Department of Chemistry, Eskisehir Osmangazi University (ESOGU), Eskisehir, 26040, Turkey.
Zinc-ion batteries (ZIBs) are emerged as a promising alternative for sustainable energy storage, offering advantages such as safety, low cost, and environmental friendliness. However, conventional aqueous electrolytes in ZIBs face significant challenges, including hydrogen evolution reaction (HER) and zinc dendrite formation, compromising their cycling stability and safety. These limitations necessitate innovative electrolyte solutions to enhance ZIB performance while maintaining sustainability.
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January 2025
School of Chemistry, South China Normal University, Guangzhou 510006, People's Republic of China.
The main limitations of aqueous nickel-zinc batteries are their relatively low energy density and short cycle life, which are inextricably linked to the limitations of nickel-based cathodes. In this study, a low-crystallinity flower-like cobalt-doped nickel hydroxide (α-Ni(OH)-0.2Co) is constructed by hydrothermal reaction and employed as high-energy-density cathode for aqueous rechargeable nickel-zinc batteries.
View Article and Find Full Text PDFTalanta
January 2025
DSM-Firmenich, Kogle Allé 4, 2970, Hørsholm, Denmark.
The development and validation of an accurate, selective, and eco-friendly capillary zone electrophoretic detection (CZE) method has been presented for concurrent measurement of inorganic and organic anions including chloride, sulfate, formic acid, citric acid, acetic acid, phosphate, and glutamic acid in Human Milk Oligosaccharides (HMOs) for the first time. An electrolyte composed of an aqueous solution of benzoic acid, 16.38 mM; l-histidine, 24.
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January 2025
Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, United States.
Aqueous sodium-ion batteries (SIBs) are gradually being recognized as viable solutions for large-scale energy storage because of their inherent safety as well as low cost. However, despite recent advancements in water-in-salt electrolyte technologies, the challenge of identifying anode materials with sufficient specific capacity persists, complicating the wider adoption of these batteries. This study introduces an innovative and straightforward approach for synthesizing vanadium oxide laser-scribed graphene (VO-LSG) composites, which function as effective anode materials in aqueous sodium-ion batteries.
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