Two cluster-oxalate frameworks (denoted as SCU-62 and SCU-65) were prepared under solvent-free conditions. They contain extra-large 16-ring channels constructed from regular Mn(SO) double six-ring units (D6Rs) and lacunary In(HPO) D6Rs, respectively. Notably, SCU-65 remains stable in both boiling water and aqueous solutions with a pH range of 3-12. It has a proton conductivity of 5.5 × 10 S cm at 85 °C under 95% relative humidity.
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Cluster-oxalate frameworks with extra-large channels: solvent-free synthesis, chemical stability, and proton conduction.
Dalton Trans
September 2019
College of Chemistry, Sichuan University, Chengdu 610064, P. R. China.
Two cluster-oxalate frameworks (denoted as SCU-62 and SCU-65) were prepared under solvent-free conditions. They contain extra-large 16-ring channels constructed from regular Mn(SO) double six-ring units (D6Rs) and lacunary In(HPO) D6Rs, respectively. Notably, SCU-65 remains stable in both boiling water and aqueous solutions with a pH range of 3-12.
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