The sol-gel/ultrasonically rout produced the novel MnS2-SiO2 nano-hetero-photocatalysts with the various ratio of MnS. Prepared nano-catalyst were investigated in the photo-degradation of methylene blue under UV light illumination. Structural and optical attributes of as-prepared nano-catalysts were evaluated by X-ray diffraction and photoelectron spectroscopy. The morphological were studied by scanning electron microscopy-EDS, and dynamic light scattering. The diffuse reflectance spectroscopy was applied to examine the band gap energy. The E values of SiO, MnS-SiO-0, MnS-SiO-1, and MnS-SiO-2 nanocomposites are 6.51, 3.85, 3.17, and 2.67 eV, respectively. The particle size of the SiO and MnS-SiO-1 nanocomposites were 100.0, and 65.0 nm, respectively. The crystallite size values of MnS-SiO-1 were 52.21 nm, and 2.9 eV, respectively. MnS-SiO nano-photocatalyst was recognized as the optimum sample by degrading 96.1% of methylene blue from water. Moreover, the influence of pH of the solution, and contact time as decisive factors on the photo-degradation activity were investigated in this project. The optimum data for pH and time were found 9 and 60 min, respectively. The photo-degradation capacity of MnS-SiO-2 is improved (96.1%) due to the low band gap was found from UV-vis DRS. The antimicrobial data of MnS-SiO were studied and demonstrated that the MnS-SiO has fungicidal and bactericidal attributes.
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http://dx.doi.org/10.1016/j.jphotobiol.2019.111579 | DOI Listing |
Pharmaceutics
January 2025
Department of Mathematical and Physical Sciences, Catholic University of Temuco, Temuco 4813302, Chile.
: A previous study investigated the in vitro release of methylene blue (MB), a widely used cationic dye in biomedical applications, from nanocellulose/nanoporous silicon (NC/nPSi) composites under conditions simulating body fluids. The results showed that MB release rates varied significantly with the nPSi concentration in the composite, highlighting its potential for controlled drug delivery. To further analyze the relationship between diffusion dynamics and the MB concentration, this study developed a finite element (FE) method to solve Fick's equations governing the drug delivery system.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
King Abdulaziz City for Science and Technology (KACST), Microelectronics and Semiconductors Institute, Mailbox 6086, Riyadh 11442, Saudi Arabia.
With growing environmental concerns and the need for sustainable energy, multifunctional materials that can simultaneously address water treatment and clean energy production are in high demand. In this study, we developed a cost-effective method to synthesize zinc oxide (ZnO) nanowires via the anodic oxidation of zinc foil. By carefully controlling the anodization time, we optimized the Zn/ZnO-5 min electrode to achieve impressive dual-function performance in terms of effective photoelectrocatalysis for water splitting and waste water treatment.
View Article and Find Full Text PDFInt J Mol Sci
January 2025
Department of Mathematical, Physical and Computer Sciences, University of Parma, 43124 Parma, Italy.
This study presents an efficient and environmentally sustainable synthesis of ZnO nanoparticles using a starch-mediated sol-gel approach. This method yields crystalline mesoporous ZnO NPs with a hexagonal wurtzite structure. The synthesized nanoparticles demonstrated remarkable multifunctionality across three critical applications.
View Article and Find Full Text PDFInt J Mol Sci
January 2025
Department of Mechanical Engineering, Faculty of Technical and Human Sciences, Sapientia Hungarian University of Transylvania, Calea Sighișoarei 2, 540485 Târgu-Mureş, Romania.
A comparative adsorption study was carried out for methylene blue (MB) and its 3,7-bis(N,N-(2-hydroxyethyl)amino)-phenothiazinium dye analog (MBI). Batch experiments employed aqueous solutions and commercial filter paper. Out of seven kinetic models tested by means of four quality statistical indicators, the pseudo-second-order, the double-exponential, and the bi-linear Weber-Morris equations were best fits.
View Article and Find Full Text PDFBeijing Da Xue Xue Bao Yi Xue Ban
February 2025
Department of Critical Care Medicine, Peking University First Hospital, Beijing 100034, China.
This study reports the diagnosis and treatment of a 26-year-old pregnant woman with severe malnutrition combined with acute pyelonephritis causing sepsis, refractory septic shock and multiple organ failure. A female patient, 26 years old, was admitted to hospital mainly due to "menelipsis for more than 19 weeks, nausea and vomiting for 20 days, fever with fatigue for 3 days". At the end of 19 weeks of intrauterine pregnancy, the patient presented with fever accompanied by urinary tract irritation.
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