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Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes. | LitMetric
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Stabilization of a new nanocomposite family by reduction of gold nanoclusters with electron-reservoir complexes.

Fangyu Fu Anthony Dedieu Wenjuan Wang Tao Chen Yongbo Song Eric Fouquet Jean-René Hamon Manzhou Zhu Didier Astruc

Chem Commun (Camb)

Department of Chemistry and Center for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China.

Published: August 2019

Four stable 19-electron Fe and Co sandwich electron-reservoirs and three hydride reservoir complexes reduce the prototypal nanocluster Au25(SR)18 (R = CH2CH2Ph) leading to a largely increased kinetic stabilization of the anionic nanocluster form compared to previously known nanocluster anion salts; these salts represent new and robust nanocomposite anionic gold clusters with 18-electron sandwich complexes as counter cations.

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 Source
http://dx.doi.org/10.1039/c9cc05260gDOI Listing

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