The title pyridazinone derivative, CHClNO, is not planar. The unsubstituted phenyl ring and the pyridazine ring are inclined to each other, making a dihedral angle of 17.41 (13)° whereas the Cl-substituted phenyl ring is nearly orthogonal to the pyridazine ring [88.19 (13)°]. In the crystal, C-H⋯O hydrogen bonds generate dimers with (10) and (24) ring motifs which are linked by C-H⋯O inter-actions, forming chains extending parallel to the axis direction. The inter-molecular inter-actions were investigated using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing that the most significant contributions to the crystal packing are from H⋯H (44.5%), C⋯H/H⋯C (18.5%), H⋯O/H⋯O (15.6%), Cl⋯H/H⋯Cl (10.6%) and C⋯C (2.8%) contacts.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6658951 | PMC |
http://dx.doi.org/10.1107/S2056989019007424 | DOI Listing |
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