Cyclotriveratrylene (CTV) is a -symmetrical macrocycle, which can be used as a chiral building block in the construction of supramolecular containers. Coupling of the CTV unit with a sucrose molecule gave enantiopure water-soluble (after deprotection) containers. The absolute configuration of the synthesized capsules was determined by NMR and ECD spectroscopies and DFT calculations.
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| http://dx.doi.org/10.1021/acs.orglett.9b02451 | DOI Listing |
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