Why is the cubic structure preferred in newly formed ice?

Phys Chem Chem Phys

Gdańsk University of Technology, Faculty of Chemistry, Department of Physical Chemistry, Narutowicza 11/12, 80-233 Gdańsk, Poland.

Published: August 2019

Molecular dynamics was employed to explain the preference for the cubic structure in newly formed crystals of ice. The results showed that in supercooled liquid water the molecules connected by hydrogen bonds are more likely to adopt relative orientations similar to the ones characteristic for cubic ice. The observed preference for certain relative orientations of molecules in the hydrogen-bonded pairs results in the higher probability of the formation of ice with the cubic structure. On that basis, it was concluded that the main reason for the increased probability of the formation of cubic ice in solidifying water is the distinctive structure of liquid water.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c9cp03705eDOI Listing

Publication Analysis

Top Keywords

cubic structure
12
newly formed
8
liquid water
8
relative orientations
8
cubic ice
8
probability formation
8
cubic
5
structure preferred
4
preferred newly
4
formed ice?
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!