A square antiprism dysprosium single-ion magnet with an energy barrier over 900 K.

Chem Commun (Camb)

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China.

Published: August 2019

Herein we report a stable and high-performance Dy(iii) single-ion magnet (SIM) showing an energy barrier of 944 K under zero dc field, with an open hysteresis loop up to 6 K. To the best of our knowledge, this is the highest energy barrier for a square antiprism as well as phosphine oxide based Dy-SIMs, reported so far.

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http://dx.doi.org/10.1039/c9cc05135jDOI Listing

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