AI Article Synopsis
- Current research on MOF luminescent sensors is limited by bulk-size structures that hinder interaction with target molecules.
- A novel two-dimensional copper-based MOF, AUBM-6, was developed using isonicotinic acid and copper(II) ions, showcasing enhanced fluorescence.
- This 2D MOF demonstrated high sensitivity in detecting solvents, particularly acetone, and effectively detected metal ions with a notable response to Pd.
Article Abstract
Current research on metal-organic framework (MOF) luminescent sensing probes focuses on the design of three-dimensional bulk-sized MOFs that in return limits their up-close interactions with targeted guest molecules. In this work, we report a two-dimensional (2D) copper-based metal-organic framework, namely, AUBM-6, synthesized via solvothermal method from isonicotinic acid linker and copper(II) ion. The resulting 2D-layered MOF crystals were highly fluorescent in their exfoliated form and, therefore, explored for detecting several solvents, where a ratiometric selectivity was shown toward acetone. Metal ion sensing was also performed, by which fluorescent detection was observed to have the highest turn-off quenching efficiency toward Pd.
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| http://dx.doi.org/10.1021/acs.inorgchem.9b01315 | DOI Listing |
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