This paper presents a review of current routes to utilize sulfur and sulfuric acid. Sulfur is a by-product from sour gas and crude oil processing and the precursor of sulfuric acid. As an oversupply is projected for the near-term future, it is prudent to investigate new sulfur applications and market domains that may facilitate a balancing of supply and demand. This consideration is especially relevant for the UAE, and the Middle East in general, due to the requirement to develop sulfur-rich sour gas resources to meet increasing energy needs. The goal of this review is to understand current sulfur oversupply, not as a problem, but as an opportunity to develop more sustainable technologies. Current routes are reviewed, and possible new applications and their potential as a sulfur sink and a sustainable alternative to existing technologies are discussed. Although sulfur is currently in oversupply, less than 5% positive balance according to Harrisson (2016), it must be noted that it is also a critical component in fertilizer production, having a direct impact on the food supply for the world's growing population. Should the world find itself in a sulfur shortage in the future (which could be possible in the long-term (beyond 2030) as a result of growth in renewable energies, shale gas/oil proliferation and population growth), this would be a much greater problem than the current slight oversupply situation, thus making it important to consider sulfur recoverability as a key factor for any sulfur sink technologies explored.
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http://dx.doi.org/10.1016/j.wasman.2019.06.002 | DOI Listing |
ACS Appl Energy Mater
January 2025
Hollingsworth and Vose, Groton, Massachusetts 01450, United States.
A low-cost method of green hydrogen production via the modification of a lead acid battery has been achieved, resulting in a hydrogen flow rate of 5.3 L min from a 20-cell string. The electrochemical behavior and catalytic effect of various metal additives on the hydrogen evolution reaction (HER) was evaluated using cyclic voltammetry.
View Article and Find Full Text PDFToxicol Rep
June 2025
Department of Environmental Engineering, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan.
The Ijen crater volcano (ICV) is one of the active volcanoes with unique environmental conditions; it is the largest lake in the world with the most extreme acidity and a blue fire phenomenon and releases toxic volcanic gases, including dangerous sulfur dioxide (SO₂). It has an impact on the environment and ecosystem. This research aimed to investigate the blue fire phenomena and toxic gas SO and characterize the environmental conditions and health effects of the ICV.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200438, China.
It is always important and fascinating to explore new organic emitters that exploit unconventional pathways to unveil their emission with unique properties, such as thermally activated delayed fluorescence (TADF). In this study, we report that the rarely explored sulfur lone pair (n) is a promising alternative, where the correlated π* → n emission can be used to attain strong TADF and thus practical OLEDs. The designed strategy incorporates several key concepts (Figure 1a), in which the persulfide aromatic spirocycle enhances spin-orbit coupling, thereby increasing the intersystem crossing rate.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Botany and Microbiology, Faculty of Science, Alexandria University, Alexandria, Egypt.
Azurin, a bacterial blue-copper protein, has garnered significant attention as a potential anticancer drug in recent years. Among twenty Pseudomonas aeruginosa isolates, we identified one isolate that demonstrated potent and remarkable azurin synthesis using the VITEK 2 system and 16S rRNA sequencing. The presence of the azurin gene was confirmed in the genomic DNA using specific oligonucleotide primers, and azurin expression was also detected in the synthesized cDNA, which revealed that the azurin expression is active.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, PR China.
Heterotrophic denitrifiers play crucial roles in global carbon and nitrogen cycling. However, their inability to oxidize sulfide renders them vulnerable to this toxic molecule, which inhibits the key enzymatic reaction responsible for reducing nitrous oxide (NO), thereby raising greenhouse gas emissions. Here, we applied microcosm incubations, community-isotope-corrected DNA stable-isotope probing, and metagenomics to characterize a cohort of heterotrophic denitrifiers in estuarine sediments that thrive by coupling sulfur oxidation with denitrification through chemolithoheterotrophic metabolism.
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