Phenanthrene degradation using Fe(III)-EDDS photoactivation under simulated solar light: A model for soil washing effluent treatment.

In this work, for the first time, the nonionic surfactant polyoxyethylene-(20)-sorbitan monooleate (Tween 80, CHO) aided soil washing effluent was treated by enhanced activation of persulfate (PS) using Fe(III)-EDDS (EDDS: ethylenediamine-N, N-disuccinic acid) complexes under simulated solar light irradiation. The performance of this system was followed via the production and reactivity of radical species (SO, HO, Cl) and degradation of phenanthrene (PHE) used as a model pollutant in soils. Different physico-chemical parameters such as the concentration of reactive species and pH were investigated through the PHE degradation efficiency. The second-order rate constants of the reactions for generated radicals with PHE and Tween 80 in solution were identified through competitive reaction experiments under steady-state conditions and application of nanosecond laser flash photolysis (LFP) as well. A kinetic approach was applied to assess the selectivity and reactivity of photo-generated radicals in aqueous medium in order to explain the observed degradation trends. This work proposes an innovative technology of management of soil washing solutions using Fe(III)-EDDS complexes and solar light for the activation of persulfate.