The reaction of Ir(CO)(acac) (acac = acetylacetonate) and KBi in ethylenediamine (en) solution produces a new archetype of a 15-vertex deltahedral hybrid, [(η-Bi)(IrCO)(μ-Bi)] (1a), from the Bi-coordination aggregation of the [Ir(CO)] cationic units, providing a feasible route towards new hybrid compounds made by the combination of Zintl anions and transition-metal carbonyl clusters.
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[(η-Bi)(IrCO)(μ-Bi)]: a new archetype of a 15-vertex deltahedral hybrid from Bi-coordination aggregation of cationic [IrCO] units.
Dalton Trans
August 2019
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
The reaction of Ir(CO)(acac) (acac = acetylacetonate) and KBi in ethylenediamine (en) solution produces a new archetype of a 15-vertex deltahedral hybrid, [(η-Bi)(IrCO)(μ-Bi)] (1a), from the Bi-coordination aggregation of the [Ir(CO)] cationic units, providing a feasible route towards new hybrid compounds made by the combination of Zintl anions and transition-metal carbonyl clusters.
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